" Synthesis of ZIF-67 in Alcoholic Solvents: Morphology and Adsorption Properties for Methylene Blue"

Document Type : Research

Authors

1 Department of Chemical Engineering, South Tehran Branch, Islamic Azad University, P. O. Box: 15847-43311, Tehran, Iran

2 Department of Environmental Research, Institute for Color Science and Technology, P. O. Box: 167654-654, Tehran, Iran.

3 Department of Textile Engineering, SR.C., Islamic Azad University, P. O. Box: 14515-775, Tehran, Iran.

10.30509/jscw.2025.167461.1219

Abstract

This study explores the green synthesis of cobalt-based ZIF-67 using methanol, ethanol, and isopropanol as solvents. Alcoholic solvents enhance the morphology, particle size control, and stability of ZIF-67, making it suitable for moisture-sensitive applications. The synthesis was performed at room temperature via reflux, avoiding hazardous solvents. XRD, FTIR, and SEM analyses confirmed the solvent’s significant influence on particle size and uniformity. Isopropanol-synthesized ZIF-67 exhibited the highest methylene blue adsorption capacity (29.1 mg/g), followed by ethanol (22.94 mg/g) and methanol (19.37 mg/g). Adsorption studies (pH 7, 0.02 g adsorbent, 7 mg/L dye, 180 min) revealed that the process follows the Langmuir isotherm, indicating a spontaneous, endothermic, monolayer adsorption. This study highlights the critical role of solvent choice in optimizing ZIF-67 properties and suggests isopropanol as a promising solvent for enhanced adsorption applications in environmental and industrial fields.

Keywords

Main Subjects

References

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Journal of Studies in Color World
Volume 15, Issue 2
April 2025
Pages 169-189

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  • Receive Date: 01 February 2025
  • Revise Date: 01 March 2025
  • Accept Date: 01 March 2025

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