مروری بر الیگومرها و مونومرهای تجدیدپذیر جهت تهیه پوشش‌های تابش‌پز

نوع مقاله : مقاله مروری

نویسنده

دانشجوی دکترا، دانشکده مهندسی پلیمر و رنگ، دانشگاه صنعتی امیرکبیر

چکیده

هدف از این مقاله، معرفی انواع گونه‌های واکنش‌پذیر حساس به نور مشتق شده از زیست توده‌ها و زیست پلیمرها است که این ترکیبات می‌توانند طی فرآیند پلیمریزاسیون نوری که فرآیندی تمیز، سریع و بدون انتشار آلاینده‌ها مانند ترکیبات آلی فرار (VOC) است، پلیمر شوند و به شکل پوشش درآیند. زیست پلیمرهای اولیه می‌توانند برای به دست آوردن پلیمرهای حساس به نور اصلاح شوند. در این گزارش، ابتدا انواع الیگوهرهای تابش‌پز معرفی می‌شوند، سپس انواع اصلی پلیمرهای طبیعی مانند لیپیدها، آمینو اسیدها (پروتئین‌ها)، کربوهیدرات‌ها، پلی ان‌ها، لاستیک طبیعی و غیره توصیف خواهندشد. در ادامه نحوه استخراج، اصلاح، استفاده یا یکپارچه‌سازی آنها در سامانه‌های پلیمریزاسیون نوری و کاربرد آنها به عنوان پوشش سطوح شرح داده می‌شود. تاکنون روش‌های مختلفی نظیر آکریلاسیون با مونومرهای اکریلیکی و جفت‌کننده تیول -انی برای اصلاح این مواد اولیه تجدیدپذیر استفاده شده است. مواد تجدید پذیر اصلاح‌‌شده می‌توانند با سازوکار پلیمریزاسیون‌های مختلف مانند رادیکالی، کاتیونی، خود شروع‌کننده و عاری از شروع‌کننده، تیول انی و غیره تهیه شوند. همچنین به ویژگی‌ها، واکنش‌پذیری، سمیت، زیست تخریب‌پذیری، زیست‌سازگاری و کاربرد نهایی این ترکیبات نیز اشاره خواهد شد.
 

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

A Review on the Renewable Oligomers and Monomers for Preparation of the Radiation Coatings

نویسنده [English]

  • Sahar Abdollahi Baghban
Polymer Engineering and Color Technology Department, Amirkabir University of Technology
چکیده [English]

The aim of this review was to describe the variety of reactive species derived from biomass that can lead to photosensitive materials through a photopolymerization process, a clean and quick process at room temperature without pollutant emission such as volatile organic compounds (VOC) to make radiation cure coatings. These biosourced macromolecules can be easily modified to obtain photosensitive or UV-reactive macromolecules. The main classes of naturally occurring molecules and macromolecules such as lipids, amino acids (proteins), carbohydrates, polyenes, natural rubber, etc. are detailed. The ways they are extracted, modified, used or integrated in photopolymerizable systems are described in relation to their applications: coatings, biomaterials, biodegradable drug delivery systems, microelectronics or optoelectronics. Different methods such as acrylation by acrylic monomers and thiol-ene coupling are used to modify these renewable feedstock use in materials. The modified renewable materials can be used in various photopolymerization such as radical, cationic, self-initiating, thiol-ene and etc. polymerization. This critical review takes into account the characteristics and reactivity of the various compounds as well as their cytotoxicity, biodegradability and their end uses.

کلیدواژه‌ها [English]

  • Radiation cure coatings
  • Renewable material
  • Vegetable oil
  • Polysaccharide
  • Protein

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مطالعات در دنیای رنگ
دوره 8، شماره 4
اسفند 1397
صفحه 51-76

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  • تاریخ دریافت: 09 دی 1397
  • تاریخ بازنگری: 27 بهمن 1397
  • تاریخ پذیرش: 12 اسفند 1397

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