مروری بر پوشش‌دهی چندکاره منسوجات با نانوذرات نقره سنتز‌شده با منابع گیاهی

نوع مقاله : مقاله مروری

نویسندگان

1 دانشیار، دانشکده فرش، دانشگاه هنر اسلامی تبریز، تبریز، ایران، صندوق‌پستی: 4567-51385.

2 دانشجوی کارشناسی ارشد، دانشگاه هنر اسلامی تبریز، تبریز، ایران، صندوق‌پستی: 4567-51385.

چکیده

در سال‌های اخیر سنتز زیستی نانوذرات فلزی نسبت به روش‌های شیمیایی و فیزیکی به دلیل فرآیند تهیه آسان، پاک، ارزان، قابل دسترس و زیست سازگاری مناسب مورد توجه بسیاری از محققان می‌‌باشد. بخش‌های مختلف گیاهان نظیر برگ، ریشه، ساقه، گل، میوه، دانه، پوست و ضایعات حاوی ترکیبات مختلف نظیر پلی‌فنل‌ها، فلاونوئیدها، تانن‌ها، آلکالوئیدها، قندها، کربوهیدرات‌ها، پروتئین‌ها و ترپنوئیدها هستند که برای سنتز زیستی نانوذرات استفاده می‌شوند. بازده سنتز نانوذرات، مقدار، شکل و اندازه آن‌ها به قدرت احیا کنندگی و پایدارسازی ترکیبات موجود در عصاره گیاهان وابسته است. نقش اصلی ترکیبات زیستی، احیا یون‌های فلزی و تبدیل آن‌ها به فلز () و همچنین پایدا‌رسازی با ایجاد یک لایه محافظ بر روی نانوذرات سنتز شده برای جلوگیری از تجمع آن‌ها می‌‌باشد. در این مقاله پیشرفت‌های اخیر در سنتز نانوذرات نقره و پوشش‌دهی آنها روی منسوجات با استفاده از بخش‌های مختلف گیاهان به دو روش کلی در محل (in situ) و خارج از محل (ex situ) مرور شده است. عوامل موثر بر بازده، شکل و اندازه نانو ذرات نقره نظیر غلظت پیش‌ساز فلزی، غلظت عصاره گیاه، دما و غیره مرور و جمع‌بندی شده است. به‌علاوه، خواص چندکاره منسوجات پوشش داده‌شده با نانوذرات نقره نظیر خواص رنگی، ضدباکتری، ضدقارچ، آنتی اکسیدانی، محافظت در برابر تابش فرابنفش و غیره نیز مورد بحث و بررسی قرار گرفته است.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

A Review on Multifunctional Coating of Textiles via Silver Nanoparticles Synthesized with Plant Sources

نویسندگان [English]

  • Siyamak Safapour 1
  • Fatemeh Liaghat 2
1 Faculty of Carpet, Tabriz Islamic Art University, P. O. BOX 51385-4567, Tabriz, Iran.
2 Faculty of Carpet, Tabriz Islamic Art University, P. O. BOX 51385-4567, Tabriz, Iran.
چکیده [English]

In recent years, compared to chemical and physical methods, the biosynthesis of metal nanoparticles has been of interest to many researchers due to its easy, clean, cheap, accessible, and biocompatible preparation process. Different parts of plants such as leaves, roots, stems, flowers, fruits, seeds, skin, and waste contain various compounds such as polyphenols, flavonoids, tannins, alkaloids, sugars, carbohydrates, proteins, and terpenoids, which are used for the biosynthesis of nanoparticles. The efficiency of nanoparticle synthesis, their amount, shape, and size depend on compounds' reducing and stabilizing power in plant extracts. The main role of biological compounds is the reduction of metal ions and their conversion to metal (M°), as well as stabilization by creating a protective layer on the synthesized nanoparticles to prevent their accumulation. In this review paper, recent advances in synthesizing silver nanoparticles and their coating on textiles using different parts of plants in two general methods, in situ and ex situ, have been reviewed. Factors affecting silver nanoparticles' efficiency, shape, and size, such as metal precursor concentration, plant extract concentration, temperature, etc., have been reviewed and summarized. In addition, the multifunctional properties of textiles coated with silver nanoparticles, such as color properties, antibacterial, antifungal, antioxidant, ultraviolet protection, etc., have also been discussed.

کلیدواژه‌ها [English]

  • Silver nanoparticles
  • Biological synthesis
  • Green synthesis
  • Multifunctional finishing of Textiles
  • Antibacterial finishing
  1. . A. Velidandi, S. Dahariya, N. Pabbathi, D. Kalivarathan, R. Baadhe, "A review on synthesis, applications, toxicity, risk assessment and limitations of plant extracts synthesized silver nanoparticles", NanoWorld J. 6, 35-60, 2020.

    1. PF. de Oliveira, RM. Torresi, F. Emmerling, PH. Camargo, "Challenges and opportunities in the bottom-up mechanochemical synthesis of noble metal nanoparticles", J. Mater. Chem. A. 8, 16114-16141, 2020.
    2. Y. Xia, Y. Xiong, B. Lim, SE. Skrabalak, "Shape‐controlled synthesis of metal nanocrystals: simple chemistry meets complex physics?" Angew. Chem. Int. Ed. 48, 60-103, 2009.
    3. CM. Crisan, T. Mocan, M. Manolea, LI. Lasca, F-A. Tăbăran, L. Mocan, "Review on silver nanoparticles as a novel class of antibacterial solutions", Appl. Sci. 11, 11-20, 2021.
    4. AC. Paiva-Santos, AM. Herdade, C. Guerra, D. Peixoto, M. Pereira-Silva, M. Zeinali, F. Mascarenhas, M. António Paranhos, F. Veiga, "Plant-mediated green synthesis of metal-based nanoparticles for dermopharmaceutical and cosmetic applications", Int. J. Pharm. 597, 120311, 2021.
    5. S. Rajeshkumar, L. Bharath, "Mechanism of plant-mediated synthesis of silver nanoparticles–a review on biomolecules involved, characterisation and antibacterial activity", Chem. Biol. Interact. 273, 219-227, 2017.
    6. M. Rehan, A. Barhoum, G. Van Assche, A. Dufresne, L. Gätjen, R. Wilken, "Towards multifunctional cellulosic fabric: UV photo-reduction and in-situ synthesis of silver nanoparticles into cellulose fabrics", Int. J. Biol. Macromol. 98, 877-886, 2017.
    7. M. Maghimaa, SA. Alharbi, "Green synthesis of silver nanoparticles from Curcuma longa L. and coating on the cotton fabrics for antimicrobial applications and wound healing activity", J. Photochem. Photobiol. 204, 111806, 2020.
    8. S. Kumari, M. Tyagi, S. Jagadevan, :Mechanistic removal of environmental contaminants using biogenic nanomaterials", Int. J. Environ. Sci. Technol. 16, 7591-606, 2019.
    9. Y. Zhou, R-C. Tang, "Facile and eco-friendly fabrication of AgNPs coated silk for antibacterial and antioxidant textiles using honeysuckle extract", J. Photochem. Photobiol. B. 178, 463-471, 2018.
    10. B. Butola, F. Mohammad, "Silver nanomaterials as future colorants and potential antimicrobial agents for natural and synthetic textile materials", RSC Adv. 6(50), 44232-47, 2016.
    11. A. Majeed, W. Ullah, AW. Anwar, A. Shuaib, U. Ilyas, P. Khalid, G. Mustafa, M. Junaid, B. Faheem, S. Ali, "Cost-effective biosynthesis of silver nanoparticles using different organs of plants and their antimicrobial applications: A review", Mater. Technol. 33, 313-20, 2018.
    12. Z. Issaabadi, M. Nasrollahzadeh, SM. Sajadi, "Green synthesis of the copper nanoparticles supported on bentonite and investigation of its catalytic activity", J. Cleaner Prod. 142, 3584-91, 2017.
    13. EE. Tanner, K. Tschulik, R. Tahany, K. Jurkschat, C. Batchelor-McAuley, RG. Compton, "Nanoparticle capping agent dynamics and electron transfer: polymer-gated oxidation of silver nanoparticles", J. Phys. Chem. C. 119, 18808-815, 2015.
    14. A. Hebeish, TI. Shaheen, ME. El-Naggar, "Solid state synthesis of starch-capped silver nanoparticles". Int. J. Biol. Macromol. 87, 70-76, 2016.
    15. CV. Restrepo, CC. Villa, "Synthesis of silver nanoparticles, influence of capping agents, and dependence on size and shape: A review", Environ. Nanotechnol. Monitor Manage. 15, 100428, 2021.
    16. F. Behzad, SM. Naghib, SN. Tabatabaei, Y. Zare, KY. Rhee, "An overview of the plant-mediated green synthesis of noble metal nanoparticles for antibacterial applications", J. Ind. Eng. Chem. 94, 92-104, 2020.
    17. M. Krifa, C. Prichard, "Nanotechnology in textile and apparel research–an overview of technologies and processes", J. Text. Inst. 111, 1778-1793, 2020.
    18. JK. PATRA, S. Gouda, "Application of nanotechnology in textile engineering: An overview", J. Eng. Technol. Res. 5, 104-111, 2013.
    19. A. Biswas, IS. Bayer, AS. Biris, T. Wang, E. Dervishi, F. Faupel, "Advances in top–down and bottom–up surface nanofabrication: Techniques, applications & future prospects", Adv. Colloid Interface Sci. 170, 2-27, 2012.
    20. VC. Karade, RB. Patil, SB. Parit, JH. Kim, AD. Chougale, VV. Dawkar, "Insights into shape-based silver nanoparticles: a weapon to cope with pathogenic attacks", ACS Sustainable Chem. Eng. 9, 12476-12507, 2021.
    21. PG. Jamkhande, NW. Ghule, AH. Bamer, MG. Kalaskar, "Metal nanoparticles synthesis: An overview on methods of preparation, advantages and disadvantages, and applications", J. Drug Delivery Sci. Technol. 53, 101174, 2019.
    22. A. Zhang, G. Zheng, CM. Lieber, "General synthetic methods", Nanowires: Springer. 15-37, 2016.
    23. KN. Thakkar, SS. Mhatre, RY. Parikh, "Biological synthesis of metallic nanoparticles", Nanomed. Nanotechnol. Biol. Med. 6, 257-262, 2010.
    24. HK. Chan, PC. Kwok, "Production methods for nanodrug particles using the bottom-up approach", Adv. Drug Delivery Rev. 63, 406-16, 2011.
    25. Y. Wang, Y. Xia, "Bottom-up and top-down approaches to the synthesis of monodispersed spherical colloids of low melting-point metals", Nano Lett. 4, 2047-50, 2004.
    26. X-F. Zhang, Z-G. Liu, W. Shen, S. Gurunathan, "Silver nanoparticles: synthesis, characterization, properties, applications, and therapeutic approaches", Int. J. Mol. Sci. 17, 1534, 2016.
    27. C. Dhand, N. Dwivedi, XJ. Loh, ANJ. Ying, NK. Verma, RW. Beuerman, R. Lakshminarayanan, S. Ramakrishna, "Methods and strategies for the synthesis of diverse nanoparticles and their applications: a comprehensive overview", Rsc Adv. 5, 105003-37, 2015.
    28. MA. Raza, Z. Kanwal, A. Rauf, AN. Sabri, S. Riaz, S. Naseem, "Size-and shape-dependent antibacterial studies of silver nanoparticles synthesized by wet chemical routes", Nanomater. 6, 74, 2016.

    30 A. Gour, NK. Jain, "Advances in green synthesis of nanoparticles", Artif. Cells Nanomed. Biotechnol. 47, 844-851, 2019.

    1. S. Iravani, H. Korbekandi, SV. Mirmohammadi, B. Zolfaghari, "Synthesis of silver nanoparticles: chemical, physical and biological methods", Res. Pharm. Sci. 9(6), 385, 2014.
    2. KM. Abou El-Nour, Aa. Eftaiha, A. Al-Warthan, RA. Ammar, "Synthesis and applications of silver nanoparticles", Arabian J. Chem. 3, 135-140, 2010.
    3. L. Kibis, A. Stadnichenko, E. Pajetnov, S. Koscheev, V. Zaykovskii, A. Boronin, "The investigation of oxidized silver nanoparticles prepared by thermal evaporation and radio-frequency sputtering of metallic silver under oxygen", Appl. Surf. Sci. 257, 404-413, 2010.
    4. M. Miranzadeh, M. Kassaee, "Solvent effects on arc discharge fabrication of durable silver nanopowder and its application as a recyclable catalyst for elimination of toxic p-nitrophenol", Chem. Eng. J. 257, 105-111, 2014.
    5. O. Kylián, A. Kuzminova, R. Štefaníková, J. Hanuš, P. Solař, P. Kúš, M. Cieslar, A. Choukourov, H. Biederman, "Silver/plasma polymer strawberry-like nanoparticles produced by gas-phase synthesis", Mater. Lett. 253, 238-41, 2019.
    6. AA. Yaqoob, K. Umar, MNM. Ibrahim, "Silver nanoparticles: various methods of synthesis, size affecting factors and their potential applications–a review", Appl. Nanosci. 10, 1369-78, 2020.
    7. OV, Kharissova, HR. Dias, BI. Kharisov, BO. Pérez, VMJ. Pérez, "The greener synthesis of nanoparticles", Trends Biotechnol. 31(4), 240-8, 2013.

    38, I. Hussain, N. Singh, A. Singh, H. Singh, S. Singh," Green synthesis of nanoparticles and its potential application", Biotechnol. Lett. 38, 545-60, 2016.

    1. Q. Sun, X. Cai, J. Li, M. Zheng, Z. Chen, C-P. Yu, "Green synthesis of silver nanoparticles using tea leaf extract and evaluation of their stability and antibacterial activity", Colloids Surf. A. 444, 226-231, 2014.
    2. T. Anju, S. Parvathy, MV. Veettil, J. Rosemary, T. Ansalna, M. Shahzabanu, S. Devika, "Green synthesis of silver nanoparticles from Aloe vera leaf extract and its antimicrobial activity,. Mater. Today: Proc. 43, 3956-60, 2021.
    3. R. Krishnasamy Sekar, A. Sridhar, B. Perumalsamy, DB. Manikandan, T. Ramasamy, "In vitro antioxidant, antipathogenicity and cytotoxicity effect of silver nanoparticles fabricated by onion (Allium cepa L.) peel extract", BioNanoSci. 10(1), 235-248, 2020.
    4. B. Khodadadi, M. Bordbar, M. Nasrollahzadeh, "Achillea millefolium L. extract mediated green synthesis of waste peach kernel shell supported silver nanoparticles: application of the nanoparticles for catalytic reduction of a variety of dyes in water", J. Colloid Interface Sci. 493, 85-93, 2017.
    5. H. Veisi, S. Hemmati, H. Shirvani, H. Veisi, "Green synthesis and characterization of monodispersed silver nanoparticles obtained using oak fruit bark extract and their antibacterial activity", Appl. Organomet. Chem. 30(6), 387-391, 2016.
    6. MA. Chowdhury, N. Hossain, M. Kchaou, R. Nandee, MBA. Shuvho, S. Sultana, "Scope of eco-friendly nanoparticles for anti-microbial activity", Curr. Res. Green and Sustainable Chem. 4, 100198, 2021.
    7. V. Soni, P. Raizada, P. Singh, HN. Cuong, S. Rangabhashiyam, A. Saini, Saini RV, Q. Van Le, AK. Nadda, TT. Le, VH. Nguyen, "Sustainable and green trends in using plant extracts for the synthesis of biogenic metal nanoparticles toward environmental and pharmaceutical advances: A review", Environ. Res. 202, 111622, 2021.
    8. M. Nasrollahzadeh, M. Sajjadi, J. Dadashi, H. Ghafuri, "Pd-based nanoparticles: Plant-assisted biosynthesis, characterization, mechanism, stability, catalytic and antimicrobial activities", Adv. Colloid Interface Sci. 276, 102103, 2020.
    9. S. Medici, M. Peana, VM. Nurchi, MA. Zoroddu, "Medical uses of silver: history, myths, and scientific evidence", J. Med. Chem. 62, 5923-43, 2019.
    10. MB. Kasiri, S. Safapour, "Exploring and exploiting plants extracts as the natural dyes/antimicrobials in textiles processing", Prog. Color Colorants Coat. 8, 87-144, 2015.
    11. M. Hosseinnezhad, K. Gharanjig, R. Jafari, H. Imani, "Green dyeing of woolen yarns with weld and madder natural dyes in the presences of biomordant", Prog. Color Colorants Coat. 14, 35-45, 2021.
    12. M. Sadeghi-Kiakhani, S. Safapour, Y. Golpazir, "Impact of chitosan-poly (amidoamine) dendreimer hybrid treatment on dyeing and color fastness properties of wool yarn with madder natural dye", Prog. Color Colorants Coat. 12, 241-50, 2019.
    13. M. Shahparvari, S. Safapour, K. Gharanjig, "Investigation of compatibility of natural dyes prangos ferulacea, madder and punica grantum shell in dyeing of woolen yarn", J. Color Sci. Technol. 13, 25-37, 2019.
    14. A. Haji, "Methods of improvement of dyeability of wool with natural dyes", J. Stud. Color World. 11, 1-16, 2021.
    15. H. Bahman, K. Gharanjig, S. Rouhani, A. Tahvili, M. Hosseinnezhad, H. Imani, A. Mahmoudi Nahavandi, "Optimization of dye extraction from madder by response surface methodology and study of dyeing properties", J. Color Sci. Technol. 14, 83-96, 2020.
    16. A. Shamsnateri, M. Veysian, "Past, present, and future of application of natural Dyes in hand-woven carpets", J. Stud. Color World. 11, 33-42, 2021.
    17. A. Haji, "Review on methods and technologies for improvement of adsorption and fastness properties of natural dyes on cotton fibers", J. Stud. Color World. 7, 33-44, 2017.
    18. M. Ghaffarzadeh, M. Edrisi, "A Review on natural pigments and the extraction methods", J. Stud. Color World. 6, 63-82, 2016.
    19. S. Mirnezhad, S. Safapour, M. Sadeghi-Kiakhani, "Review on the properties and application of cochineal natural colorant in different industries", J. Studies Color World. 5, 33-46, 2016.
    20. S. Rouhani, N. Alizadeh, S. Salimi, T. Haji-Ghasemi, "Ultrasonic assisted extraction of natural pigments from rhizomes of curcuma longa L", Prog. Color Colorants Coat. 2, 103-113, 2009.
    21. F. Malekan, M. Khajeh Mehrizi M, S. Veysian, "The Effect of nanomaterials on dyed handmade carpet with weld natural dye", J. Color Sci. Technol. 14, 203-214, 2020.
    22. NM. Alabdallah, MM. Hasan, "Plant-based green synthesis of silver nanoparticles and its effective role in abiotic stress tolerance in crop plants", Saudi J. Biol. Sci. 28, 5631-39, 2021.
    23. N. Čuk, M. Šala, M. Gorjanc, "Development of antibacterial and UV protective cotton fabrics using plant food waste and alien invasive plant extracts as reducing agents for the in-situ synthesis of silver nanoparticles, Cellul. 28, 3215-33, 2021.
    24. M. Mahiuddin, P. Saha, B. Ochiai, "Green synthesis and catalytic activity of silver nanoparticles based on Piper chaba stem extracts", Nanomater. 10, 1777, 2020.
    25. M. Behravan, AH. Panahi, A. Naghizadeh, M. Ziaee, R. Mahdavi, A. Mirzapour, "Facile green synthesis of silver nanoparticles using Berberis vulgaris leaf and root aqueous extract and its antibacterial activity", Int. J. Biol Macromol. 124, 148-154, 2019.
    26. B. Venkatadri, E. Shanparvish, M. Rameshkumar, MV. Arasu, NA. Al-Dhabi, VK. Ponnusamy, P. Agastian, "Green synthesis of silver nanoparticles using aqueous rhizome extract of Zingiber officinale and Curcuma longa: In-vitro anti-cancer potential on human colon carcinoma HT-29 cells", Saudi J. Biol. Sci. 27, 2980-6, 2020.
    27. M. Bindhu, M. Umadevi, GA. Esmail, NA. Al-Dhabi, MV. Arasu, "Green synthesis and characterization of silver nanoparticles from Moringa oleifera flower and assessment of antimicrobial and sensing properties", J. Photochem. Photobiol., B. 205, 111836, 2020.
    28. B. Kumar, K. Smita, L. Cumbal, A. Debut, :Green synthesis of silver nanoparticles using Andean blackberry fruit extract", Saudi J. Biol Sci. 24, 45-50, 2017.
    29. HM. Ibrahim, "Green synthesis and characterization of silver nanoparticles using banana peel extract and their antimicrobial activity against representative microorganisms", J. Radiat. Res. Appl. Sci. 8(3), 265-75, 2015.
    30. V. Dhand, L. Soumya, S. Bharadwaj, S. Chakra, D. Bhatt, .Sreedhar, "Green synthesis of silver nanoparticles using Coffea arabica seed extract and its antibacterial activity", Mater. Sci. Eng., C 58, 36-43, 2016.
    31. S. Donga, S. Chanda, "Facile green synthesis of silver nanoparticles using Mangifera indica seed aqueous extract and its antimicrobial, antioxidant and cytotoxic potential (3-in-1 system)", Artif. Cells Nanomed. Biotechnol. 49(1), 292-302, 2021.
    32. MM. Khalil, EH. Ismail, KZ. El-Baghdady, D. Mohamed, "Green synthesis of silver nanoparticles using olive leaf extract and its antibacterial activity", Arabian J. Chem. 7, 1131-9, 2014.
    33. V. Kumar, S. Singh, B. Srivastava, R. Bhadouria, R. Singh, "Green synthesis of silver nanoparticles using leaf extract of Holoptelea integrifolia and preliminary investigation of its antioxidant, anti-inflammatory, antidiabetic and antibacterial activities", J. Environ. Chem. Eng. 7, 103094, 2019.
    34. Y. Rout, S. Behera, AK. Ojha, P. Nayak, "Green synthesis of silver nanoparticles using Ocimum sanctum (Tulashi) and study of their antibacterial and antifungal activities", J. Microbiol. Antimicrob. 4, 103-9, 2012.
    35. OA. L dos Santos, I. de Araujo, FD. da Silva, MN. Sales, MA. Christoffolete, BP. Backx, "Surface modification of textiles by green nanotechnology against pathogenic microorganisms", Curr. Res. Green Sustainable Chem. 4, 100206, 2021.
    36. AA. El-Sayed, A. Amr, OM. Kamel, MM. El-Saidi, AE. Abdelhamid, "Eco-friendly fabric modification based on AgNPs@ Moringa for mosquito repellent applications", Cellul. 27, 8429-42, 2020.
    37. J. Seetha, Um. Mallavarapu, P. Akepogu, A. Mesa, VR. Gollapudi, H. Natarajan, VR. Anumakonda, "Biosynthesis and study of bimetallic copper and silver nanoparticles on cellulose cotton fabrics using Moringa oliefiera leaf extraction as reductant", Inorg. Nano-Metal Chem. 50(9), 828-35, 2020.
    38. P. Sivaranjana, E. Nagarajan, N. Rajini, M. Jawaid, AV. Rajulu, "Cellulose nanocomposite films with in situ generated silver nanoparticles using Cassia alata leaf extract as a reducing agent", Int. J. Biol. Macromol. 99, 223-32, 2017.
    39. PS. Vankar, D. Shukla, "Biosynthesis of silver nanoparticles using lemon leaves extract and its application for antimicrobial finish on fabric", Appl. Nanosci. 2,163-168, 2012.
    40. A. Syafiuddin, MA. Fulazzaky, S. Salmiati, M. Roestamy, M. Fulazzaky, K .Sumeru, Z. Yusop, "Sticky silver nanoparticles and surface coatings of different textile fabrics stabilised by Muntingia calabura leaf extract", SN Appl. Sci. 2(4), 1-10, 2020.
    41. KJ. Rao, T. Korumilli, "Instant synthesis of silver particles on silk fibres: Characterization and antimicrobial study", Compos. Commun. 18, 32-6, 2020.
    42. R. Pusphalatha, B. Ashok, N. Hariram, AV. Rajulu, "Nanocomposite polyester fabrics with in situ generated silver nanoparticles using tamarind leaf extract reducing agent", Int. J. Polym. Anal. Charact. 24, 524-32, 2019.
    43. Q. Zhou, J. Lv, Y. Ren, J. Chen, .Gao, Z. Lu, C. Wang, "A green in situ synthesis of silver nanoparticles on cotton fabrics using Aloe vera leaf extraction for durable ultraviolet protection and antibacterial activity", Textile Research Journal. 87, 2407-19, 2017.
    44. G. Mamatha, A. Varada Rajulu, K. Madhukar, "In situ generation of bimetallic nanoparticles in cotton fabric using aloe vera leaf extract, as a reducing agent", J. Nat. Fibers. 17, 1121-9, 2020.
    45. M. Zou, M. Du, H. Zhu, C. Xu, N. Li, Y. Fu, "Synthesis of silver nanoparticles in electrospun polyacrylonitrile nanofibers using tea polyphenols as the reductant", Polym. Eng. Sci. 53, 1099-108, 2013.
    46. S. Ravindra, YM. Mohan, NN. Reddy, KM. Raju, "Fabrication of antibacterial cotton fibres loaded with silver nanoparticles via "Green Approach"", Colloids Surf. A . 367(1-3), 31-40, 2010.
    47. AK. Jha, K. Prasad, "Green synthesis and antimicrobial activity of silver nanoparticles onto cotton fabric: an amenable option for textile industries", Adv. Mater. Lett. 7, 42-6, 2016.
    48. J. Filipic, D. Glazar, S. Jerebic, D. Kenda, A. Modic, B. Roskar, I. Vrhovski, D. Stular, B. Golja, S. Smolej, B. Tomsic, "Tailoring of antibacterial and UV-Protective cotton fabric by an in situ synthesis of silver particles in the presence of a sol-gel matrix and sumac leaf extract", Tekstilec. 63, 4-13, 2020.
    49. D. Štular, E. Savio, B. Simončič, M. Šobak, I. Jerman, I. Poljanšek, A. Ferri, B .Tomšič, "Multifunctional antibacterial and ultraviolet protective cotton cellulose developed by in situ biosynthesis of silver nanoparticles into a polysiloxane matrix mediated by sumac leaf extract", Appl. Surf. Sci. 563, 150361, 2021.
    50. S. Andra, J. Jeevanandam, M. Muthalagu, MK. Danquah, "Surface cationization of cellulose to enhance durable antibacterial finish in phytosynthesized silver nanoparticle treated cotton fabric", Cellul. 28, 5895-910, 2021.
    51. Y. Zhou, Z-Y. Yang, R-C. Tang, "Green and facile fabrication of AgNPs@ silk for colorful and multifunctional textiles using baicalin as a natural reductant", J. Cleaner Prod. 170, 940-9, 2018.
    52. S. Siengchin, P. Boonyasopon, V. Sadanand, AV. Rajulu, "Nanocomposite cellulose fabrics with in situ generated silver nanoparticles by bioreduction method", J. Ind. Text. 1528083720924731, 2020.
    53. M. Sathishkumar, K. Sneha, Y-S. Yun, "Immobilization of silver nanoparticles synthesized using Curcuma longa tuber powder and extract on cotton cloth for bactericidal activity", Bioresour. Technol. 101, 7958-65, 2010.
    54. H. Barani, MN. Boroumand, S. Rafiei, "Application of silver nanoparticles as an antibacterial mordant in wool natural dyeing: synthesis, antibacterial activity, and color characteristics", Fibers Polym. 18, 658-65, 2017.
    55. S. Natarajan, D. Gupta, "Novel method for biosynthesis of silver nanoparticles using melanin and its application on wool to impart antimicrobial activity", Indian J. Fibre Text. Res. 45, 183-9, 2020.
    56. SN. Aboutorabi, M. Nasiriboroumand, P. Mohammadi, H. Sheibani, H. Barani, "Biosynthesis of silver nanoparticles using safflower flower: structural characterization, and its antibacterial activity on applied wool fabric", J. Inorg. Organomet. Polym. Mater. 28, 2525-32, 2018.
    57. M. Balamurugan, S. Saravanan, T. Soga, "Coating of green-synthesized silver nanoparticles on cotton fabric", J. Coat. Technol. Res. 14, 735-45, 2017.
    58. P. Velmurugan, M. Cho, S-M. Lee, J-H. Park, S. Bae, B-T. Oh, "Antimicrobial fabrication of cotton fabric and leather using green-synthesized nanosilver", Carbohydr. Polym. 106, 319-25, 2014.
    59. KF. Hasan, PG. Horváth, A. Horváth, T. Alpár, "Coloration of woven glass fabric using biosynthesized silver nanoparticles from Fraxinus excelsior tree flower", Inorg. Chem. Commun. 126, 108477, 2021.
    60. M. Sadeghi-Kiakhani, AR. Tehrani-Bagha, FS. Miri, E. Hashemi, M. Safi, "Eco-Friendly Procedure for Rendering the Antibacterial and Antioxidant of Cotton Fabrics via Phyto-Synthesized AgNPs With Malva sylvestris (MS) Natural Colorant", Front. Bioeng. Biotechnol. 9, 814374, 2021.
    61. S. Mohammadalinejhad, H. Almasi, M. Esmaiili, "Simultaneous green synthesis and in-situ impregnation of silver nanoparticles into organic nanofibers by Lythrum salicaria extract: Morphological, thermal, antimicrobial and release properties", Mater. Sci. Eng., C. 105, 110-115, 2019.
    62. MN. Boroumand, M. Montazer, H. Barani, "Biocompatible stabilize silver nanoparticles and their antimicrobial activity", Adv. Sci. Lett. 22, 616-21, 2016.
    63. MN. Boroumand, M. Montazer, V. Dutschk, "Biosynthesis of silver nanoparticles using Reseda Luteola L. and their antimicrobial activity", DE REDACTIE. 64, 123, 2013.
    64. Z. Yu, H. He, J. Liu, Y. Li, X. Lin, C. Zhang, M. Li, "Simultaneous dyeing and deposition of silver nanoparticles on cotton fabric through in situ green synthesis with black rice extract", Cellul. 27, 1829-43, 2020.
    65. H. Jiang, R. Guo, R. Mia, H. Zhang, S. Lü, F. Yang, S. Mahmud, H. Liu, "Eco-friendly dyeing and finishing of organic cotton fabric using natural dye (gardenia yellow) reduced-stabilized nanosilver: full factorial design", Cellul. 29, 2663-79, 2022.
    66. AH. Patil, SA. Jadhav, KD. Gurav, SR. Waghmare, GD. Patil, VD. Jadhav, SH. Vhanbatte, PV. Kadole, KD. Sonawane, PS. Patil, "Single step green process for the preparation of antimicrobial nanotextiles by wet chemical and sonochemical methods", J. Text. Inst. 111, 1380-8, 2020.
    67. P. Velmurugan, J. Shim, H. Kim, J-M. Lim, SA. Kim, Y-S. Seo, JW. Kim, K. Kim, BT. Oh, "Bio-functionalization of cotton, silk, and leather using different in-situ silver nanoparticle synthesis modules, and their antibacterial properties", Res. Chem. Intermed. 46, 999-1015, 2020.
    68. P. Sharma, S. Pant, S. Rai, RB. Yadav, S. Sharma, V. Dave, "Green synthesis and characterization of silver nanoparticles by Allium cepa L. to produce silver nano‐coated fabric and their antimicrobial evaluation", Appl. Organomet. Chem. 32, e4146, 2018.
    69. N. Yang, W-H. Li, "Mango peel extract mediated novel route for synthesis of silver nanoparticles and antibacterial application of silver nanoparticles loaded onto non-woven fabrics", Ind. Crops Prod. 48, 81-8, 2013.
    70. B. Butola, A. Gupta, A. Roy, "Multifunctional finishing of cellulosic fabric via facile, rapid in-situ green synthesis of AgNPs using pomegranate peel extract biomolecules", Sustainable Chem. Pharm. 12, 100135, 2019.
    71. MN. Boroumand, M. Montazer, F. Simon, J. Liesiene, Z. Šaponjic, V .Dutschk, "Novel method for synthesis of silver nanoparticles and their application on wool", Appl. Surf. Sci. 346, 477-83, 2015.
    72. M. Nasiriboroumand, M. Montazer, H. Barani, "Preparation and characterization of biocompatible silver nanoparticles using pomegranate peel extract", J. Photochem. Photobiol. B. 179, 98-104, 2018.
    73. B. Butola, A. Kumar, "Green chemistry based in-situ synthesis of silver nanoparticles for multifunctional finishing of chitosan polysaccharide modified cellulosic textile substrate", Int. J. Biol. Macromol. 152, 1135-45, 2020.
    74. M. Rehan, NS. Elshemy, K. Haggag, A. Montaser, GE. Ibrahim, "Phytochemicals and volatile compounds of peanut red skin extract: Simultaneous coloration and in situ synthesis of silver nanoparticles for multifunctional viscose fibers", Cellul. 27, 9893-912, 2020.
    75. B. Butola, D. Verma, "Facile synthesis of chitosan-silver nanoparticles onto linen for antibacterial activity and free-radical scavenging textiles", Int. J. Biol. Macromol. 133, 1134-41, 2019.
    76. T-H. Cheng, Z-Y. Yang, R-C. Tang, A-D. Zhai, "Functionalization of silk by silver nanoparticles synthesized using the aqueous extract from tea stem waste", J. Mater. Res. Technol. 9, 4538-4549, 2020.
    77. J. Sheikh, I. Bramhecha, "Multi-functionalization of linen fabric using a combination of chitosan, silver nanoparticles and Tamarindus Indica L. seed coat extract", Cellul. 26, 8895-905, 2019.
    78. KF. Hasan, X. Liu, Z. Kóczán, PG. Horváth, M. Bak, L. Bejó, A. Horváth, T. Alpár, "Nanosilver coating on hemp/cotton blended woven fabrics mediated from mammoth pine bark with improved coloration and mechanical properties", J. Text. Inst. 1-10, 2021.
    79. AV. Rao, B. Ashok, M. Umamahesh, V. Chandrasekhar, GV. Subbareddy, AV. Rajulu, "Preparation and properties of silver nanocomposite fabrics with in situ-generated silver nano particles using red sanders powder extract as reducing agent", Int. J. Polym. Anal. Charact. 23, 493-501, 2018.
    80. KF. Hasan, PG. Horváth, Z. Kóczán, M. Bak, A. Horváth, T. Alpár, "Coloration of flax woven fabrics using Taxus baccata heartwood‐mediated nanosilver", Color. Technol. 138, 146-56, 2022.
    81. R. Aladpoosh, M. Montazer, N. Samadi, "In situ green synthesis of silver nanoparticles on cotton fabric using Seidlitzia rosmarinus ashes", Cellul. 21, 3755-66, 2014.
    82. M. Taheri, M. Montazer, AB. Rezaie, "A Cleaner affordable method for production of bactericidal textile substrates by in situ deposition of ZnO/Ag nanoparticles", Fibers Polym. 22, 2792-802, 2021.
    83. R. Aladpoosh, M. Montazer, "Nano-photo active cellulosic fabric through in situ phytosynthesis of star-like Ag/ZnO nanocomposites: Investigation and optimization of attributes associated with photocatalytic activity", Carbohyd. Polym. 141, 116-25, 2016.
    84. M. Shabbir, F. Mohammad, "Multifunctional AgNPs@ Wool: Colored, UV-protective and antioxidant functional textiles", Appl. Nanosci. 8, 545-55, 2018.
    85. VP. Veeraraghavan, ND. Periadurai, T. Karunakaran, S. Hussain, KM. Surapaneni, X. Jiao, "Green synthesis of silver nanoparticles from aqueous extract of Scutellaria barbata and coating on the cotton fabric for antimicrobial applications and wound healing activity in fibroblast cells (L929)", Saudi J. Biol. Sci. 28, 3633-40, 2021.

    124. A. Rohani Shirvan, S. Kordjazi, A. Bashari, "Environmentally friendly finishing of cotton fabric via star-like silver micro/nano particles synthesized with neem/salep", J. Nat. Fibers. 18, 1472-80, 2021