جذب ترکیبات کروم III از پساب رنگی صنعت چرم توسط نانوذرات سیلیس

نوع مقاله : پژوهشی

نویسندگان

1 کارشناسی ارشد، دانشکده مهندسی شیمی، دانشگاه صنعتی سهند تبریز، تبریز، ایران، صندوق‌پستی: 1996-51335.

2 دانشیار، دانشکده مهندسی شیمی، دانشگاه صنعتی سهند تبریز، تبریز، ایران، صندوق‌پستی: 1996-51335.

3 استاد، گروه مهندسی شیمی‌دانشگاه صنعتی ارومیه، ارومیه، ایران، صندوق‌پستی: 57155-419.

چکیده

در تحقیق حاضر از نانوذرات سیلیس تهیه شده از پوسته برنج به روش ترسیب متداول و فراصوت برای تصفیه پساب واحد تولید چرم استفاده است. اثر غلظت سود، pH ترسیب و زمان پیرسازی بر بازدهی جذب سیلیس به کمک روش طراحی مرکب مرکزی مورد مطالعه قرار گرفته است. نتایج آزمایشات نشان داد که خاکستر پوسته برنج به عنوان پیش ماده مورد استفاده در تهیه سیلیس، باید در محلول رقیق سود با غلظت 5/0 مولار حل شود و pH ترسیب نیز باید در حدود 0/9 کنترل گردد تا جاذبی با عملکرد مناسب برای حذف ترکیبات کروم III حاصل شود. هر چند سطح ویژه سیلیس بدست آمده با روش رسوب‌دهی متداول، بزرگ‌تر از مقدار آن برای جاذب حاصل از ترسیب تحت امواج فراصوت است، توزیع اندازه خلل دارای نقش اساسی در جذب ترکیبات کروم است. ترسیب تحت فراصوت منجر به منافذ بزرگی می‌شود که در محدوده 38-4 نانومتر توزیع می‌شوند و نفوذ ترکیبات کروم را حتی در محیط‌های اسیدی تسهیل می‌کند.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Adsorption of Chromium III Species from Colorant Tannery Wastewater by Silica Nano-Particles

نویسندگان [English]

  • Zahra Hosseine Amirhandeh 1
  • Amin Salem 2
  • ُShiva Salem 3
1 Faculty of Chemical Engineering, Sahand University of Technology, Tabriz, Iran, P. O. Box: 51335-1996.
2 Faculty of Chemical Engineering, Sahand University of Technology, Tabriz, Iran, P. O. Box: 51335-1996
3 Faculty of Chemical Engineering, Urmia University of Technology, Urmia, Iran, P. O. Box: 419-57155
چکیده [English]

The current research uses silica nanoparticles produced from rice husk through conventional and sonochemical precipitation to treat industrial tannery wastewater. The effects of NaOH concentration, precipitation pH, and ageing time on adsorption properties were studied via the central composite design (CCD) method. The obtained results indicated that rice husk ash, as a precursor used in the preparation of silica, should be dissolved in the dilute NaOH solution, 0.5 mol L-1, and precipitation pH should be controlled at the level of 9.0 to achieve an adsorbent with proper performance. Although the surface area of powder produced conventionally is larger than that obtained by the sonochemical method, the pore size distribution plays an effective role in the adsorption of Cr III compounds. The precipitation under sonication leads to large pores distributed in the 4-38 nm range, facilitating the diffusion of chromium compounds even in acidic environments.

کلیدواژه‌ها [English]

  • Rice husk
  • tannery wastewater
  • chromium species
  • meso-silica powder
  • ultrasound-assisted precipitation
  • adsorption

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  • تاریخ دریافت: 14 آذر 1401
  • تاریخ بازنگری: 21 اردیبهشت 1402
  • تاریخ پذیرش: 07 خرداد 1402

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