ساخت کامپوزیت MOF-5/ هواژل سلولزی و بررسی عملکرد آن در حذف ماده رنگزای متیلن بلو

نوع مقاله : پژوهشی

نویسندگان

1 کارشناسی ارشد، دانشکده عمران، گروه مهندسی محیط‌زیست، دانشگاه علم و صنعت ایران، تهران، ایران، کد‌پستی: ۱۶۸۴۶۱۳۱۱۴.

2 دانشیار، دانشکده عمران، گروه مهندسی محیط‌زیست، دانشگاه علم و صنعت ایران، تهران، ایران، کدپستی: ۱۶۸۴۶۱۳۱۱۴.

3 دانشیار، دانشکده شیمی، گروه شیمی، دانشگاه علم و صنعت ایران، تهران، ایران، کدپستی: ۱۶۸۴۶۱۳۱۱۴.

4 دکتری، گروه پژوهشی مواد رنگزای آلی، پژوهشگاه رنگ، تهران، ایران، صندوق‌پستی: 654-167654.

10.30509/jscw.2024.167288.1188

چکیده

چارچوب‌های فلزی- آلی مواد متخلخلی هستند که به دلیل ویژگی‌های منحصربه‌فردی مانند قابلیت اصلاح‌پذیری، مساحت سطح زیاد، پایداری شیمیایی و مقاومت مکانیکی بالا ازجمله پیشتازترین جاذب‌ها در حوزه جذب و شناسایی آلاینده‌ها می‌باشند. یکی از مشکلات اساسی این ساختارها در فرایند جذب، جداسازی آن‌ها در انتهای فرایند جذب به دلیل ساختار پودری شکل آن‌ها می‌باشد. در این مطالعه برای حل این مشکل از هواژل و کامپوزیت ساختن آن با چارچوب فلزی- آلی سنتز شده استفاده شد. در این پژوهش کامپوزیت MOF-5/ هواژل سلولزی با استفاده از سلولز استخراج‌شده از گیاه پامپاس ساخته شد و اثر آن برای حذف ماده رنگزای آلی (متیلن بلو) از محیط‌های آبی بررسی شد. مشخصه یبلو کامپوزیت ساخته شده، به‌وسیله آنالیزهای تصویر میکروسکوپ الکترونی، پراش اشعه ایکس و IR بررسی گردید. میزان جذب آلاینده‌ (ماده رنگزای کاتیونی متیلن بلو) به‌وسیله دستگاه  UV- visنشان داد که میزان حذف ماده رنگزای کاتیونی در pH قلیایی مقدار 95 درصد در مدت ‌زمان 60 دقیقه است. همچنین اثر pH، زمان، غلظت مواد رنگزا بررسی گردید. استفاده مجدد از ماده جاذب مشخص نمود که بعد از 3 بار استفاده تنها 5 درصد از قدرت جاذب کاسته شد.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Synthesis of MOF-5 / Cellulose Aerogel Composite and Investigation of Its Performance in Removing Methylene Blue Dye

نویسندگان [English]

  • Mohammad Shiri 1
  • Majid Hosseinzadeh 2
  • Shahrzad Javanshir 3
  • Soudeh Shiri 4
1 Faculty of Civil Engineering, Department of Environmental Engineering, Iran University of Science and Technology, P. O. Code: 1684613114, Tehran, Iran.
2 Faculty of Civil Engineering, Department of Environmental Engineering, Iran University of Science and Technology, P. O. Code: 1684613114, Tehran, Iran.
3 Faculty of Chemistry, Department of Chemistry, Iran University of Science and Technology, P. O. Code: 1684613114, Tehran, Iran
4 Department of Organic Colorants, Institute for Color Science and Technology, P. O. Box. 16765-654, Tehran, Iran
چکیده [English]

Metal-organic framework (MOF) aerogels are porous materials with unique characteristics such as tunability, high surface area, chemical stability, and high mechanical strength, making them among the leading adsorbents in pollutant adsorption and identification. One of the fundamental challenges with these structures during the adsorption process is their separation at the end of the adsorption process due to their powdery nature. To address this issue, this study used aerogels and their composites with synthesized metal-organic framework (MOF). In this research, a composite of MOF-5/cellulose aerogel was fabricated using cellulose extracted from the cotton plant, and its effectiveness in removing an organic dye (methylene blue) from aqueous environments was investigated. Characterization was performed using electron microscopy, X-ray diffraction, and IR analysis. The adsorption of the pollutant (methylene blue cationic dye) was measured using a UV-vis spectrophotometer, showing a removal efficiency of 95% at alkaline pH within a 60-minute time frame. The effects of pH, time, and dye concentration were also examined. The reusability of the adsorbent material was demonstrated, with only a 5% reduction in adsorption capacity after three cycles of use.

کلیدواژه‌ها [English]

  • MOF-5/ cellulose aerogel composite
  • Pampas
  • Wastewater treatments
  • Adsorption capacity
  • Methylene blue dye

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مطالعات در دنیای رنگ
دوره 14، شماره 3
مهر 1403
صفحه 193-203

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  • تاریخ دریافت: 20 اسفند 1402
  • تاریخ بازنگری: 10 تیر 1403
  • تاریخ پذیرش: 11 تیر 1403

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