مروری بر پلیمرهای قالب یونی در حذف و شناسایی رنگ‌سنجی سرب: تهیه، سازوکار و کاربرد

نوع مقاله : مقاله مروری

نویسندگان

1 کارشناسی ارشد، گروه محیط زیست، دانشکده معدن، نفت و ژئوفیزیک، دانشگاه صنعتی شاهرود، شاهرود، ایران، صندوق‌پستی: 316.

2 استادیار، گروه پژوهشی محیط زیست و رنگ، پژوهشگاه رنگ، تهران، ایران، صندوق پستی: 654-16765.

3 دانشیار، گروه محیط زیست، دانشکده معدن، نفت و ژئوفیزیک، دانشگاه صنعتی شاهرود، شاهرود، ایران، صندوق پستی: 316.

10.30509/jscw.2024.167332.1195

چکیده

تجمع یون‌‌های فلزات سنگین در اکوسیستم‌ها، تهدیدی برای انسان و سایر جانداران می‌باشد و می‌تواند باعث بیماری‌های مختلفی مانند سرطان، بیماری‌های پوستی، قلبی- عروقی و اختلالات خونی شود. بنابراین جذب و شناسایی یون‌های فلزات سنگین به طور مداوم مورد نیاز است. روش جذب به دلیل انعطاف‌پذیری، سرعت و سهولت استفاده، تاثیر کمتر بر محیط‌زیست و هزینه کمتر مورد استقبال قرار گرفته است. از میان انواع جاذب‌ها، پلیمر‌های قالب یونی به دلیل انتخاب‌پذیری زیاد، فاکتور تغلیظ بالا و پایداری شیمیایی مناسب، برای شناسایی و حذف یون‌های مختلف فلزی مورد توجه قرار گرفته‌اند. این مطالعه فهرستی از مطالعات انجام شده طی دو دهه گذشته را مورد بررسی قرار می‌دهد. در بخش اول، روش‌ها، اجزا و روش‌های اصلی بسپارش برای تهیه پلیمر قالب یونی توضیح داده شده‌اند و در بخش دوم متغیرهای سنتز، عملکرد جذب و تحلیل پلیمر‌های قالب یونی به عنوان جاذب فلزات سنگین ارائه شده‌اند. بعلاوه، با توجه به کاربرد پلیمرهای قالب یونی در تهیه حسگرها، در بخش پایانی، به کاربرد پلیمرهای قالب یونی در شناسایی رنگ سنجی فلزات سنگین از جمله سرب پرداخته خواهد شد که بدین‌منظور استفاده از لیگاندهای اختصاصی جهت ایجاد تغییر رنگ مناسب از اهمیت ویژه‌ای برخوردارند. لذا، نتایج این تحقیقات حاکی از کاربرد موفقیت آمیز پلیمرهای قالب یونی برای حذف و شناسایی رنگ سنجی کاتیون‌های سرب از محیط‌های آبی می‌باشند.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

A Review of Ion-imprinted Polymer for the Removal and Colorimetric Detection of Lead: Preparation, Mechanism and Application

نویسندگان [English]

  • Leila Peik-Rayekan 1
  • Nargess Yousefi-Limaee 2
  • Kumars Seifpanahi-Shabani 3
1 Department of Mining Engineering, Faculty of Mining, Petroleum and Geophysics, Shahrood University of Technology, P. O. Box: 316, Shahrood, Iran.
2 Department of Environmental Research, Institute for Color Science and Technology, P. O. Box: 16765-654, Tehran, Iran.
3 Department of Mining Engineering, Faculty of Mining, Petroleum and Geophysics, Shahrood University of Technology, P. O. Box: 316, Shahrood, Iran.
چکیده [English]

The accumulation of heavy metal ions in ecosystems poses a significant threat to humans and other organisms, leading to various diseases such as cancer, skin diseases, cardiovascular and blood disorders. Therefore, the adsorption and detection of heavy metal ions is constantly needed. The adsorption method is favored due to its flexibility, speed, ease of use, minimal environmental impact, and cost-effectiveness. 00Among various adsorbents, ion-imprinted polymers (IIPs) have garnered attention for the identification and removal of metal ions due to their high selectivity, significant concentration factor, and robust chemical stability .This study reviews research conducted over the past two decades. The first section covers the primary polymerization methods, components, and techniques used in producing IIPs. The second section delves into synthesis parameters, adsorption performance, and the use of IIPs as sorbents for heavy metals. Additionally, the final section discusses the application of IIPs in the colorimetric detection of heavy metals, particularly lead ions. The use of specific ligands to induce a detectable color change is emphasized as a key factor in this process. The results of this study highlight the successful application of IIPs for both the removal and colorimetric detection of lead ions in aqueous solutions.

کلیدواژه‌ها [English]

  • Heavy metals
  • Ion-imprinted polymer
  • Lead
  • Adsorption
  • Colorimetric detection

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مطالعات در دنیای رنگ
دوره 14، شماره 3
مهر 1403
صفحه 253-264

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  • تاریخ دریافت: 26 خرداد 1403
  • تاریخ بازنگری: 14 مرداد 1403
  • تاریخ پذیرش: 28 مرداد 1403

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