حذف رنگزای مالاکیت گرین از پساب با استفاده از کامپوزیت زیستی چارچوب فلز – آلی (ZIF-67) و پلیمر (کربوکسی متیل سلولز)

نوع مقاله : پژوهشی

نویسندگان

1 دانشجوی کارشناسی ارشد، دانشکده شیمی، دانشگاه گیلان، رشت، ایران، کد‌پستی: ۴۱۹۹۶۱۳۷۷۶.

2 دانشیار، دانشکده شیمی، دانشگاه گیلان، رشت، ایران، کد‌پستی: ۴۱۹۹۶۱۳۷۷۶.

3 استاد، گروه محیط زیست، پژوهشگاه رنگ، تهران، ایران، صندوق‌پستی: 654-167654.

4 دانشجوی پسادکتری، گروه محیط زیست، پژوهشگاه رنگ، تهران، ایران، صندوق‌پستی: 654-167654.

10.30509/jscw.2024.167336.1197

چکیده

در این تحقیق، چارچوب ایمیدازولات زئولیتی 67 (ZIF-67) و کامپوزیت زیستی کربوکسی متیل سلولز CMC/ZIF-67 (CMC/ZIF-67) سنتز شد. مواد سنتز‌شده با آنالیز‌های مختلف شناسایی شدند. سپس از کربوکسی متیل سلولز و کامپوزیت زیستی CMC/ZIF-67 برای حذف رنگزای مالاکیت گرین استفاده شد. نتایج نشان داد که قابلیت حذف رنگزا با کامپوزیت زیستی (35/92 درصد) بیشتر از پلیمر کربوکسی متیل سلولز (41/9 درصد) است. با افزایش مقدار جاذب، درصد حذف مالاکیت گرین نیز افزایش ‌‌می‌یابد. با افزایش مقدار جاذب، مکان‌های فعال سطح جاذب در دسترس‌‌‌تر‌ است و درصد حذف رنگزا بیشتر ‌‌می‌شود. درصد حذف رنگزا در مقادیر 1، 2، 3 و 4 میلی‌گرم جاذب کامپوزیت به ترتیب 25، 54، 79 و 35/92 درصد بود. با افزایش غلظت رنگزا، میزان حذف رنگزا کاهش یافت. میزان حذف رنگزا در غلظت‌های 20، 30، 40 و 50 میلی گرم در لیتر با کامپوزیت به ترتیب 35/92، 85، 79 و 71 درصد بود. وجود حلقه‌های ایمیدازول در ساختار ZIF-67 به عنوان لیگاند ‌‌می‌تواند یکی از دلایل اصلی ظرفیت جذب بالای کامپوزیت زیستی باشد. با توجه به پیوند‌های دوگانه در حلقه‌های ایمیدازول، برهم‌کنش‌های انباشتگی Π-Π با حلقه‌های آروماتیک مالاکیت گرین رخ ‌‌می‌دهد. این برهم‌کنش ویژه کامپوزیت زیستی را قادر می‌سازد تا ظرفیت بالای مالاکیت گرین را جذب کند. جذب رنگزا توسط کامپوزیت زیستی CMC/ZIF-67 از ایزوترم لانگمویر و سینتیک شبه مرتبه دوم پیروی ‌‌می‌کند.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Removal of Malachite Green dye from wastewater using metal-organic mold biocomposite (ZIF-67) and polymer (carboxymethyl cellulose)

نویسندگان [English]

  • Sahar Ayar 1
  • Hassan Tajik 2
  • Niyaz Mohammad Mahmoodi 3
  • Hadi Fallah Moafi 2
  • Bahareh Rabeie 4
1 Department of Chemistry, Faculty of Science, University of Guilan, P. O. Code: 4199613776, Rasht, Iran.
2 Department of Chemistry, Faculty of Science, University of Guilan, P. O. Code: 4199613776, Rasht, Iran.
3 Department of Environmental Research, Institute for Color Science and Technology, P. O. Box: 167654-654, Tehran, Iran.
4 Department of Environmental Research, Institute for Color Science and Technology, P. O. Box: 167654-654, Tehran, Iran.
چکیده [English]

In this research, the zeolitic imidazolate framework 67 (ZIF-67) and carboxymethyl cellulose (CMC)/ZIF-67 biocomposite (CMC/ZIF-67) were synthesized. Different analyses were used to characterize the synthesized materials. Then, carboxymethyl cellulose and CMC/ZIF-67 biocomposite were used to remove the dye (Malachite Green: MG). The results showed that the dye removal capability of biocomposite (92.35%) is higher than that of carboxymethyl cellulose polymer (9.41%). As the adsorbent dose increases, the removal percentage of MG also increases. As the adsorbent dose increases, the active sites of the adsorbent surface are more accessible, and the dye removal percentage is higher. The dye removal percentage in 1, 2, 3, and 4 mg of composite adsorbent was 25, 54, 79, and 92.35%, respectively. With the increase in dye concentration, the amount of dye removal decreased. The dye removal in 20, 30, 40, and 50 mg/L concentrations with composite was 92.35, 85, 79 and 71%, respectively. The presence of imidazole rings in the structure of ZIF-67 as a ligand can be one of the main reasons for the high adsorption capacity of the biocomposite. Due to the double bonds in the imidazole rings, Π-Π stacking interactions occur with the aromatic rings of MG. This special interaction enables the biocomposite to adsorb the high capacity of MG. The isotherm and kinetics of dye adsorption by CMC/ZIF-67 biocomposite followed the Langmuir isotherm and pseudo-second-order kinetics.
 

کلیدواژه‌ها [English]

  • Synthesis and characterization
  • Biocomposite metal-organic framework (ZIF-67)
  • Polymer (carboxymethyl cellulose)
  • Removal of organic
  • pollutant (dye)
  • Wastewater

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مطالعات در دنیای رنگ
دوره 14، شماره 4
دی 1403
صفحه 285-301

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  • تاریخ دریافت: 02 تیر 1403
  • تاریخ بازنگری: 19 شهریور 1403
  • تاریخ پذیرش: 24 شهریور 1403

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