بررسی کارآیی فوتوکاتالیزی نانوکامپوزیت ‌GQD/MIL101 برای تخریب مالاکیت سبز تحت تابش نور مرئی

نوع مقاله : پژوهشی

نویسندگان

1 پژوهشگر پسا دکتری، گروه محیط زیست، پژوهشگاه رنگ، تهران، ایران، صندوق پستی: 657-167654.

2 کارشناسی ارشد، گروه محیط زیست، پژوهشگاه رنگ، تهران، ایران، صندوق پستی: 657-167654.

10.30509/jscw.2025.167482.1223

چکیده

این مطالعه سنتز سبزکامپوزیت چارچوب فلز-آلی/ گرافن کوانتوم دات  GQD/MIL101 را با استفاده از روشی ساده در یک حلال آبی ارائه می‌کند. نسبت های مولی متفاوت گرافن کوانتوم دات به  MIL101که به صورت GQD/MIL101-5، GQD/MIL101-10 و GQD/MIL101-15 نشان داده شده، سنتز شد و از نظر فعالیت فوتوکاتالیزی مورد ارزیابی قرار گرفت. در مورد بهترین کامپوزیت، بهینه‌سازی عوامل کلیدی مانند محتوای گرافن کوانتوم دات ، غلظت آلاینده، pH اولیه محلول آلاینده، و مقدار فوتوکاتالیست ارزیابی شد. فعالیت فوتوکاتالیزی به طور خاص از طریق واکنش فوتو- فنتون با استفاده از مالاکیت سبز به عنوان یک آلاینده هدف ارزیابی گردید که میزان تخریب قابل توجه و حدود99 درصد بود. آزمایش‌های گیرانداز، رادیکال‌های هیدروکسیل را به‌عنوان فعال‌ترین و مؤثرترین گونه‌هایی که در ‌فرایند فوتوکاتالیزی مشارکت دارند، شناسایی کردند. پس از شش چرخه عملیاتی، فوتوکاتالیست بازیابی و پایداری قابل توجهی را نشان داد، که بر پتانسیل آن برای کاربردهای عملی در تصفیه پساب تاکید می‌کند.

کلیدواژه‌ها

موضوعات

عنوان مقاله [English]

Exploring the Photocatalytic Efficacy of GQD/MIL101 Nanocomposites for the Degradation of Malachite Green under Visible Light Irradiation

نویسندگان [English]

  • Bahareh Rabeie 1
  • Faezeh Nasrollahi 2
1 Department of Environmental Research, Institute for Color Science and Technology, P. O. Box: 167654-654, Tehran, Iran.
2 Department of Environmental Research, Institute for Color Science and Technology, P. O. Box: 167654-654, Tehran, Iran.
چکیده [English]

This study presents the green synthesis of the metal-organic framework/graphene quantum dot composite GQD/MIL101 using a simple method with water solvent. Composites were synthesized in different molar ratios of graphene quantum dots to MIL101, labeled as GQD/MIL101-5, GQD/MIL101-10, and GQD/MIL101-15, and assessed for photocatalytic activity. For the most effective composite (GQD/MIL101-15), key parameters such as pollutant concentration, initial pH of the solution, and photocatalyst dosage were optimized. The photocatalytic activity was assessed through the Photo-Fenton reaction using malachite green as the target pollutant, achieving an impressive degradation rate of approximately 99%. Scavenging experiments identified hydroxyl radicals as the most active and effective species participating. After six operational cycles, the photocatalyst showed remarkable recovery and stability, which emphasizes its potential for practical applications in wastewater treatment.
 
 

کلیدواژه‌ها [English]

  • GQD/MIL101
  • Nanocomposite
  • Green chemistry
  • Photo-Fenton reaction
  • Malachite green

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    77. Bagheri A, Hoseinzadeh H, Hayati B, Mahmoodi NM, Mehraeen E, Post-synthetic functionalization of the metal-organic framework: Clean synthesis, pollutant removal, and antibacterial activity. J Environ Chem Eng 2021;9:104590. https://doi.org/10.1016/j.jece.2020.104590.
    78. Foroughifar N, Mobinikhaledi A, Rabeie B, Jalili L, DABCO as a mild and efficient catalyst for the synthesis of tetrahydropyrimidines. Rev Roum Chim 2013;58:491-495.
    79. Mahmoodi NM, Bakhtiari M, Oveisi M, Mahmoodi B, Hayati B, Green synthesis of eco-friendly magnetic metal-organic framework nanocomposites (AlFum-graphene oxide) and pollutants (dye and pharmaceuticals) removal capacity from water. Mater Chem Phys. 2023;302:127720.https://doi.org/10.1016/j.matchemphys.2023.127720.
    80. Shokrgozar A, Seifpanahi-Shabani K, Mahmoodi B, Mahmoodi NM, Khorasheh F, Baghalha M, Synthesis of Ni-Co-CNT nanocomposite and evaluation of its photocatalytic dye (Reactive Red 120) degradation ability using response surface methodology. Desalin Water Treat 2021;216:389-400. https://doi.org/10.5004/dwt. 2021.26 804.
    81. Ahmadi S, Mahmoodi B, Kazemini M, Mahmoodi NM, Photocatalytic degradation of dye (Reactive Red 198) and pharmaceutical (tetracycline) using MIL-53 (Fe) and MIL-100 (Fe): catalyst synthesis and pollutant degradation. Pigm Resin Technol. 2023;52:357-368. https://doi.org/10.1108/ PRT-05-2022-0067.
    82. Mahmoodi NM, Hosseinabadi‐Farahani Z, Chamani H, Dye adsorption from single and binary systems using NiO‐MnO2 nanocomposite and artificial neural network modeling. Environ Prog Sustain. 2017;36:111-119. https://doi.org/10.1002/ep.12452.
    83. Mahmoodi NM, Ghadirli MM, Hayati B, Mahmoodi B, Rabeie B, Synthesis of ZIF-8 composite (g-C3N4@ ZIF-8/Ag3PO4) as a catalyst for the malachite green and tetracycline degradation. Inorg Chem Commun. 2025; 177:114345. https://doi.org/10.1016/j.inoche. 2025. 114345.

    85. Dousti S, Mahmoodi B, Bijari M, Shahbazi A,Investigating the Effect of Various Precursors in the Synthesis and Improvement of the Photocatalytic Performance of Graphite Carbon Nitride in the Degradation of Rhodamine B Dye Under Visible Light. J Color Sci Tech. 2024;18(2):135-150. https://doi.org/10.30509/JCST.2024. 167291.1224 [In Persian].

مطالعات در دنیای رنگ
دوره 15، شماره 2
اردیبهشت 1404
صفحه 191-209

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  • تاریخ دریافت: 13 اسفند 1403
  • تاریخ بازنگری: 21 فروردین 1404
  • تاریخ پذیرش: 22 فروردین 1404

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