بررسی عوامل مؤثر بر حذف مواد رنگزا از پساب با استفاده از نانوکامپوزیت‌‌های مختلف: مطالعه مروری

نوع مقاله : مقاله مروری

نویسندگان

1 دکتری، گروه مهندسی شیمی و پلیمر، دانشکده فنی و مهندسی، دانشگاه آزاد اسلامی واحد تهران جنوب، تهران، ایران، صندوق‌پستی: 43311/15847.

2 دانشیار، مرکز تحقیقات فناوری نانو، دانشگاه آزاد اسلامی واحد تهران جنوب، تهران، ایران، صندوق‌پستی: 43311/15847.

3 دانشیار، دانشکده مهندسی شیمی و پلیمر، دانشگاه آزاد اسلامی، واحد تهران جنوب، تهران، ایران، صندوق‌پستی: 43311/15847.

4 گروه شیمی دانشکده علوم پایه دانشگاه آزاد اسلامی واحد شهرقدس، شهرقدس، تهران، ایران

5 استاد، گروه پژوهشی محیط زیست و رنگ، پژوهشگاه رنگ، تهران، ایران، صندوق‌پستی: 654-167654.

چکیده

در سال‌های اخیر، صنعت نساجی بیش از 50 درصد از پساب‌‌های رنگی در جهان را تولید کرده است. آب پاکیزه نقش مهمی در زندگی انسان‌ها ، موجودات آبزی و محصولات کشاورزی دارد . وجود مواد رنگزا در آبها به دلیل سمیتی که دارند باعث کیفیت نامطلوب ، به خطر انداختن سلامتی آنها شده و تغییراتی را در محیط‌زیست ایجاد می‌کند. روش‌های مختلفی جهت تصفیه پساب وجود دارد که براساس تحقیقاتی که انجام شده نشان می‌دهد که امروزه بیشتر از روش جذب سطحی برای تصفیه پساب به دلیل ارزان بودن، سادگی و مقرون‌به‌صرفه بودن استفاده می‌شود. در این مقاله بررسی حذف مواد رنگزا از پساب با استفاده از نانوکامپوزیت‌های مختلف انجام شده است که تاثیر جذب سطحی با نانوکامپوزیت ها براساس عوامل موثر بر جذب سطحی شامل زمان تماس، غلظت اولیه ، اثر دما وpH  محلول می‌باشند مورد بررسی قرار گرفتند. نانوکامپوزیتها تاثیر زیادی در حذف مواد رنگزا دارند و می‌توانند با کیفیت خوبی، تصفیه پساب را انجام دهند. در این پژوهش از نانوکامپوزیت‌های کربن فعال ، نانولوله‌های کربنی ، نانوذرات نقره ، فریت روی، ZnO،TiO2 ، Fe3O4 و نانوذرات آهن صفر ظرفیتی معمولا برای رنگبری پساب استفاده می‌شوند. در این مقاله نتایج نشان می‌دهد که نانوکامپوزیت‌های مختلف نوید بخش آینده‌ای امیدوار‌کننده برای تصفیه پساب رنگی می‌باشند.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

Investigating Factors Affecting the Removal of dyestuff from Wastewater Using Different Nanocomposites: A Review Study

نویسندگان [English]

  • Ali Hosseinian Naeini 1
  • Mohammad Reza Kalaee 2 3
  • Omid Moradi 4
  • Niyaz Mohammad Mahmoodi 5
1 Department of Chemical and Polymer Engineering, Tehran South Branch, Islamic Azad University, P. O. Box: 15847/43311,Tehran, Iran.
2 Nanotechnology Research Centre, Tehran South Branch, Islamic Azad University, P. O. Box: 15847/43311, Tehran, Iran.|Department of Chemical and Polymer Engineering, Tehran South Branch, Islamic Azad University, P. O. Box: 15847/43311, Tehran, Iran.
3 Nanotechnology Research Centre, Tehran South Branch, Islamic Azad University, P. O. Box: 15847/43311, Tehran, Iran.|Department of Chemical and Polymer Engineering, Tehran South Branch, Islamic Azad University, P. O. Box: 15847/43311, Tehran, Iran.
4 Department of Chemistry, Faculty of Science, Shahr-e-Qods Branch, Islamic Azad University, Tehran, Iran
5 Department of Environmental Research, Institute for Color Science and Technology, P. O. Box: 167654-654, Tehran, Iran.
چکیده [English]

In recent years, the textile industry has produced more than 50 % of the colored wastewater in the world. Clean water is essential in the lives of humans, aquatic organisms, and agricultural products. Due to their toxicity, dyestuff in water causes adverse quality, endangers their health, and causes environmental changes. There are different methods for wastewater treatment, which, based on the research, shows that today's surface absorption method is mainly used for wastewater treatment due to its cheapness, simplicity, and cost-effectiveness. In this article, the removal of dyestuff from wastewater was investigated using different nanocomposites, and the effect of adsorption with nanocomposites was investigated based on factors affecting adsorption, including contact time, initial concentration, the effect of temperature, and pH of the solution. Adsorbents significantly impact removing dyestuff and can perform wastewater treatment with good quality. This research used activated carbon nanocomposites, carbon nanotubes, silver nanoparticles, zinc ferrite, ZnO, TiO2, Fe3O4 and zero-valent iron nanoparticles for wastewater decolorization. In this article, the results show that different nanocomposite adsorbents are promising. They are a promising future for the treatment of colored wastewater.

کلیدواژه‌ها [English]

  • Dye removal
  • Nanocomposites
  • Adsorption
  • Wastewater
1.        T. Robinson, G. McMullan, R. Marchant, P. Nigam, "Remediation of dyes in textile effluent: a critical review on current treatment technologies with a proposed alternative", Bioresour. Technol. 77, 247–255, 2001.
2.        A. Mittal, J. Mittal, L. Kurup, "Adsorption isotherms, kinetics and column operations for the removal of hazardous dye, tartrazine from aqueous solutions using waste materials-bottom ash and de-oiled soya, as adsorbents", J. Hazard. Mater. 136, 567–578, 2006.
3.        N.M. Mahmoodi, S. Soltani-Gordefaramarzi. “Dye removal from single and quaternary systems using surface modified nanoparticles: isotherm and kinetics studies”. Prog. Color. Colorants and Coat. 9, 85-97, 2016.
4.        M.A. Behnajady, N. Modirshhla, N. Daneshvar, M. Rabbani, "Photocatalytic degradation of an azo dye in a tubular continuous-flow photoreactor with immobilized TiO2 on glass plates", Chem. Eng. J. 127 , 167–176,2007.
5.        V.K. Gupta, Suhas, "Application of low-cost adsorbents for dye removal—a review", J. Environ. Manage. 90, 2313–2342, 2009.
6.        M.A. Rauf, S.B. Bukallah, A. Hamadi, A. Sulaiman, F. Hammadi, "The effect of operational parameters on the photoinduced decoloration of dyes using a hybrid catalyst V2O5/TiO2", Chem. Eng. J. 129, 167–172, 2007.
7.        A. Demirbas, "Agricultural based activated carbons for the removal of dyes from aqueous solutions: a review", J. Hazard. Mater. 167, 1–9, 2009.
8.        X. Luo, L. Zhang, "High effective adsorption of organic dyes on magnetic cellulose beads entrapping activated carbon", J. Hazard. Mater. 171, 340–347, 2009.
9.        S. Iijima, "Helical microtubules of graphitic carbon", Nature. 354, 56–58, 1991.
10.  R.B. Rakhi, K. Sethupathi, S. Ramaprabhu, "Field emission from carbon nanotubes on a graphitized carbon fabric", Carbon. 46, 1656–1663, 2008.
11.  A.L.M. Reddy, S. Ramaprabhu, "Nanocrystalline Metal Oxides dispersed multiwalled carbon nanotubes as supercapacitor  electrode", J. Phys. Chem. C. 111, 7727–7734, 2007.
12.  N. Jha, S. Ramaprabhu, "Thermal conductivity studies of metal dispersed multiwalled carbon nanotubes in water and ethylene glycol based nanofluids", J.Appl. Phys. 106 , 084317–84326,2009.
13.  W.H. Shin, H.M. Jeong, B.G. Kim, J.K. Kang, J.W.Choi, "Nitrogen-doped multiwall carbon nanotubes for lithium storage with extremely high capacity", Nano Lett. 12, 2283-2288, 2012. 
14.  X. Liu, M. Antonietti, "Molten salt activation for synthesis of porous carbon nanostructures and carbon sheets", Carbon. 69, 460-466, 2014.
15.  J .Wang, S. Kaskel, "KOH activation of carbon-based materials for energy storage", J. Mater. Chem. 22, 3710-23725,2012.
16.  S. Wang, C. Xiao, Y. Xing, H. Xu, S. Zhang, "Carbon nanofibers/nanosheets hybrid derived from cornstalks as a sustainable anode for Li-ion batteries", J. Mater. Chem. 3, 6742-6746, 2015.
17.  M. Abdel Salam, M .Mokhtar, S.N. Basahel, S.A. A.l. Thabaiti, A.Y.Obaid, "Removal of chlorophenol from aqueous solution by multi-walled carbon nanotubes: Kinetic and thermodynamic studies", J. Alloys .Compd. 500, 87-92,2010. 
18.  H .Al-Johani, M. Abdel Salam, "Kinetics and thermodynamic study of aniline adsorption by multi-walled carbon nanotubes from aqueous solution", J .Colloid Interface Sci. 360, 760-767, 2011.
19.  X. Xin, Q. Wei, J .Yang, L .Yan, R. Feng, G .Chen, B. Du, L.Hi, "Highly efficient removal of heavy metal ions by aminefunctionalized mesoporous Fe3O4 nanoparticles", J. Chem. Eng. 184,132-140,2012. 
20.  N .Khandoker, S.C. Hawkins, R. Ibrahim, C.P. Huynh, F. Deng, "Tensile strength of spinnable multiwall carbon nanotubes", Procedia. Eng. 10, 2572-2578, 2011. 
21.    D.W.H Fam, A. Palaniappan, A.I.Y Tok, B. Liedberg, S.M. Moochhala. "A review on technological aspects influencing commercialization of carbon nanotube sensors", Sens.  Actuators. B. Chem. 157, 1-7, 2011. 
22.  A.Verma, M. Nath, N. Malhan, A. K.Gangulia, "Improved optical properties in nanocrystalline Ce:YGG garnets via normal and reverse strike co-precipitation method", Mater. Lett. 93, 21-24, 2013. 
23.  T.V.N. Padmesh, k. Vijayaraghavan, G. Sekaran, M. Velan, "Application of Azolla rongpong on biosorption of acid red 88, acid green 3, acid orange 7 and acid blue 15 from synthetic solutions", J. Chem. Eng. 122, 55–63, 2006.
24.  A. Sanjabi , S. Azizian, M. Torabi, M. A. Zolfigol, M. Yarie, "On the applicability of triazine-based covalent organic polymer as adsorbent for dye removal from aqueous solution", Microporous. Mesoporous. Mater. 348, 112367, 2023. 
25.  H. Nguyen, T.J-C. Bollinger, E.C. Lima, R-S. Juang, "How to avoid mistakes in treating adsorption isotherm data (liquid and solid phases): Some comments about correctly using Radke-Prausnitz nonlinear model and Langmuir equilibrium constant",J. Environ. Manage. 325, 116475, 2023.
26.  Y .Bulut, H.Aydın, "A kinetics and thermodynamics study of methylene blue adsorption on wheat shells", Desalin. 194, 259–67, 2006.
27.  A. R. Tehrani-Bagha, H.Nikkar, N. M. Mahmoodi, M. Markazi, F. M. Menger, "The sorption of cationic dyes onto kaolin: kinetic, isotherm and thermodynamic studies", Desalination. 266, 274–280, 2011.
28.  I.D. Mall, V.C. Srivastava, N.K. Agarwal, I.M. Mishra , "Removal of Congo red from aqueous solution by bagasse fly ash and activated carbon: kinetic study and equilibrium isotherm analyses", Chemosphere .61,492–501,2005.
29.  C.H. Liu, J.J. Li, H.L. Zhang, B.R. Li, Y. Guo, "Structure dependent interaction between organic dyes and carbon nanotubes" ,Colloids .Surfaces. A .Physicochem .Eng .Asp. 313–314, 9–12, 2008. 
30.    S. Wang, C.W. Ng, W. Wang, Q. Li, Z. Hao, "Synergistic and competitive adsorption of organic dyes on multiwalled carbon nanotubes", Chem. Eng. J. 197, 34–40, 2012. 
31.   A. Rodríguez, G. Ovejero, J. L. Sotelo, M. Mestanza , J. García , "Adsorption of dyes on carbon nanomaterials from aqueous solutions", J. Environ .Sci. Heal. Part .A. 45, 1642–1653, 2010. 
32.  H.Y. Lin, J. Zhao, G. Song, J. Luan, X.X. Liu, G.C. Liu,  "High quality and high performance adsorption of Congo red using as-grown MWCNTs synthesized over a Co-MOF as a catalyst precursor: via the CVD method", Dalt Trans . 46, 17067–17073, 2017. 
33.  L. Ma, X. Dong, M. Chen , L. Zhu, C. Wang, F. Yang, Y. Dong,  "Fabrication and water treatment application of carbon nanotubes (CNTs)-based composite membranes: a Review", Membranes. 7, 16, 2017. 
34.  S. Hosseinzadeh, H. Hosseinzadeh, S .Pashaei, Z .Khodaparast , "Synthesis of magnetic functionalized MWCNT nanocomposite through surface RAFT co-polymerization of acrylic acid and N-isopropyl acrylamide for removal of cationic dyes from aqueous solutions", Ecotoxicol .Environ. Saf. 161, 34–44, 2018. 
35.  M. Oveisi, M.A. Asli, N.M. Mahmoodi, "MIL-Ti metal-organic frameworks (MOFs) nanomaterials as superior adsorbents: Synthesis and ultrasound-aided dye adsorption from multicomponent wastewater systems", J. Hazard. Mater. 347, 123–140, 2018.
36.  L Ai, C .Zhang, F. Liao , Y.Wang, M. Li, L. Meng, J. Jiang , "Removal of methylene blue from aqueous solution with magnetite loaded multi-wall carbon nanotube: kinetic, isotherm and mechanism analysis", J. Hazard.Mater. 198, 282–290, 2011.
37.  H .Qi, C .Qian ,J. Liu , "Synthesis of uniform double-walled carbon nanotubes using iron disilicide as catalyst", Nano. Lett . 7, 2417– 2421, 2007.
38.  S. Soroush, N.M. Mahmoodi, B. Mohammadnezhad, A. Karimi, "Activated carbon (AC)- Metal-organic framework (MOF) composite: Synthesis, characterization and dye removal", Korean J. Chem .Eng. 39, 2394–2404, 2022.
39.  Y. Zeng, L. Zhao, W. Wu, G. Lu, F. Xu, Y. Tong, W. Liu, J. Du, "Enhanced adsorption of malachite green onto carbon nanotube/polyaniline composites", J. Appl .Polym Sci.127, 2475–2482, 2013. 
40.  N.B. Singh, G. Nagpal, S.R. Agrawal, "Water purification by using Adsorbents: A Review", Environ. Technol. Innov. 11, 187–240, 2018.
41.  A. Dabrowski, "Adsorption—from theory to practice", Adv Colloid Interface Sci, 93, 135, 2001.
42.  S. Allen, B. Koumanova,"Decolourisation of water/wastewater using adsorption", J. Univ .Chem .Technol .Metall . 40, 175–92, 2005.
43.  L. Rani, , A.L. Srivastav, J. Kaushal, , X.C. Nguyen ,  "Recent advances in nanomaterial developments for efficient removal of Hg(II) from water", Environ .Sci .Pollut .Res.  29,  62851–62869 ,2022.
44.  N.M. Mahmoodi, O. Masrouri, "Cationic dye removal ability from multicomponent system by magnetic carbon nanotube", J. Solution .Chem. 44 , 1568–1583, 2015.
45.  A.K. Mishra, T. Arockiadoss, S. Ramaprabhu, "Study of removal of azo dye by functionalized multi walled carbon nanotubes", J. Chem. Eng. 162,1026–1034, (2010). 
46.  Q. Liu, W. Deng, Q. Wang, X. Lin, L. Gong, C. Liu, W. Xiong, X. Nie, "An efficient chemical precipitation route to fabricate 3D flower-like CuO and 2D leaf-like CuO for degradation of methylene blue", Adv. Powder .Technol. 31 , 1391–1401, 2020.
47.  G.Crini, "Non-conventional low-cost adsorbents for dye removal: a review", Bioresour .Technol . 97,1061–85,2006.
48.  O. Gok, A.S. O¨zcan, A.O¨zcan , "Adsorption behavior of a textile dye of Reactive Blue 19 from aqueous solutions onto modified bentonite ", Appl. Surf. Sci. 256, 5439–43, 2010.
49.  R. Rehman, S. J. Muhammad, M. Arshad, "Brilliant Green and Acid Orange 74 Dyes Removal from Water by Pinus roxburghii Leaves in Naturally Benign Way: An Application of Green Chemistry", J. Chem. 2019, 10, 2019. 
50.  H. Zhao , Z-X. Liang , Z-Z. Gao , "Facile preparation of floatable carboxymethyl cellulose-based composite hydrogel for efficient removal of organic dyes" , Colloids. Interface .Sci. Commun . 49, 100637, 2022.  
51.  A. R. Tehrani-Bagha, N. M. Mahmoodi, M. Markazi, E. Talaee, "Removal of a cationic dye from wastewater by lowcost kaolin", J. Color .Sci. Technol. 2009 3, 145- 155.
52.  S. E. Abdelazeem, M. El-T. Ashraf, M. Abd El-M. Eman, M. El-S.Gehan, "Zero Valent Iron Nanoparticle-Loaded Nanobentonite Intercalated Carboxymethyl Chitosan for Efficient Removal of Both Anionic and Cationic Dyes", ACS Omega. 6, 6348−6360,2021.
53.  P. Waranusantigul, P. Pokethitiyook, M. Kruatrachue, E.S. Upatham, "Kinetics of basic dye (methylene blue) biosorption by giant duckweed (Spirodela polyrrhiza) ", J. Environ.  Pollut. 125, 385–392,2003.
54.  J. Xu, D.Xu ,Z. Bicheng, "Adsorptive removal of an anionic dye Congo red by flower-like hierarchical magnesium oxide (MgO)-graphene oxide composite microspheres", Appl. Surf. Sci. 435, 1136-1142, 2018. 
55.  H.Sun, S-Y. Lee, S-J. Park, "Bimetallic CuPd alloy nanoparticles decorated ZnO nanosheets with enhanced photocatalytic degradation of methyl orange dye", J. Colloid .Interface. Sci. 629, 87-96,2023.
56.  F.D. Ardejani, K.H. Badii, N.L. Yousefi, N.M .Mahmoodi, M. Arami, S.Z. Shafaei, A.R. Mirhabibi, "Numerical modelling and laboratory studies on the removal of Direct Red 23 and Direct Red 80 dyes from textile effluents using orange peel, a low-cost adsorbent", Dyes .Pigm. 73, 178-185,2007. 
57.  P. Parthipan, M.A .Al-Dosary, A.A. Al-Ghamd , A. Subramania , "Eco-friendly synthesis of reduced graphene oxide as sustainable photocatalyst for removal of hazardous organic dyes", J. King .Saud .Univ. Sci. 33, 101438, 2021.
58.  P. Parthasarathy, S. Sajjad  , J. Saleem  , M. Alherbawi  , G. Mckay , "A Review of the Removal of Dyestuffs from Effluents onto Biochar", Separations . 9, 139,2022.
59.  M. Mazarji, G. Nabi-Bidhendi, N.M. Mahmoodi, "One-pot synthesis of a re duce d graphene oxide–ZnO nanorod composite and dye decolorization modeling", J. Taiwan.Inst Chem. 80, 439–451, 2017.
60.  C. Chen, J. Hu, D. Shao, J. Li, X.Wang, "Adsorption behavior of multiwall carbon nanotube/iron oxide magnetic composites for Ni(II) and Sr(II) ", J. Hazard. Mater. 164, 923-928, 2009.
61.  S. Saxena, A.S.M. Raja, "Natural Dyes: Sources, Chemistry, Application and Sustainability Issues. In: Muthu, S. (eds) Roadmap to Sustainable Textiles and Clothing", J.T.S.F.T. 37-80, 2014.  
62.  Y.S ,Ho, C.C .Chiang , "Sorption studies of acid dye by mixed sorbents", Adsorption . 7, 139-147, 2001. 
63.  S. Kadolph , "Natural Dyes: A Traditional Craft Experiencing New Attention", The Delta .Kappa. Gamma. Bulletin. 75, 14, 2008. 
64.  G. Crini, "Non-conventional low-cost adsorbents for dye removal: a review", Bioresour. Technol. 97, 1061-1085, 2006.
65.  E. Forgacs, T .Cserhati, G. Oros , "Removal of synthetic dyes from wastewater: a review", Environ. Int.  30, 953-971, 2004.
66.  M. Muthukumar, N. Selvakumar , "Studies on the effect of inorganic salts on decolouration of acid dye effluents by ozonation", Dyes. Pigm.  62, 221-228, 2004.
67.  S.T. Ong, C.K. Lee, Z. Zainal , "Removal of basic and reactive dyes using ethylene diamine modified rice hull", Bioresour .Technol.  98, 2792-2799, 2007.
68.  Z.Bingul,"Determination of affecting parameters on removal of methylene blue dyestuff from aqueous solutions using natural clay: Isotherm, kinetic, and thermodynamic studies", J. Mol. Struct. 1250, 131729, 2022.
69.  M. Purkait, S. DasGupta, S. De, "Adsorption of eosin dye on activated carbon and its surfactant based desorption", J. Environ. Manage.76, 135-142, 2005.
70.  H. Ali, "Biodegradation of synthetic dyes—a review", Water. Air.Soil. Pollut. 213, 251-273, 2010.
71.  P. Ka. Yeow  , S. W. Wong  , T. Hadibarata  , "Removal of Azo and Anthraquinone Dye by Plant Biomass as Adsorbent – A Review", Biointerface. Res. Appl. Chem. 11, 8218 – 8232, 2021.
72.  K. Bing Tan , M.T. Vakili , B. Amini Horri , P. E. Poh , A. Z. Abdullah , B. Salamatinia, "Adsorption of dyes by nanomaterials: Recent developments and adsorption mechanisms", Sep. Purif. Technol.150 , 229–242,2015. 
73.  A. Vashisht, R. Rai, S. Thakur, S. Kondal, K. Ashish Singh, Manju, D. Sharma , V.Gilhotra  ,  "Anaerobic Processes in Dye Removal. In: Khadir, A., Muthu, S.S. (eds) Biological  Approaches in Dye-Containing Wastewater", S.T.P.P.M.C. Springer. Singapore. 95-118, 2022. 
74.  Z.Karim, , A. P. Mathew, M.Grahn , J .Mouzon, , K. Oksman , "Nanoporous membranes with cellulose nanocrystals as functional entity in chitosan: Removal of dyes from water", Carbohydr. Polym. 112, 668–676, 2014.
75.  R. Laib, S. Amokrane-Nibou, D. Nibou , M. Trari, "Recovery of recycled paper in the removal of the textile dye basic yellow 28: characterization and adsorption studies", Nord. Pulp Pap. Res. J. 2019.
76.  R. A. Diyanati Tilaki, D. Balarak, M. Ghasemi, "Study Survey of Efficiency Agricultural Weast in Removal of Acid Orang 7(AO7) Dyes from Aqueous Solution: Kinetic and Equilibrium Study", Iran. J. Health. Sci. 2,51-61,2014.
77.  A. H. Mahvi and B. Heibati, "Removal of Reactive Red 120 and Direct Red 81 dyes from aqueous solutions by Pumice", Res.J.Chem .Environ. 16, 2012. 
78.  Mohammad,Lazem H. Aboud, Alaa H. Jassim, "Study of Molecular Electronic Energy Levels of Malachite Green Dye Rajaa K", AIP .Conf. Proc. 2144, 030022 ,2019.
79.  M. A. M. Abo-State , Y. E. Saleh  and H. A. Hazaa, "Decolorization of Congo Red dye by bacterial isolates", J. Eco. Heal. Env. 5, 2, 41-48 , 2017.
80.  M.A. El Hajj Hassan and M.M. El Jamal, "Kinetic Study of the Electrochemical Oxidation of Methylene Blue with Pt Electrode ", Port. Electrochim. Acta. 30, 351-359, 2012.
81.  L. Singh, "Biodegradation of Synthetic Dyes: A Mycoremediation Approach for Degradation/ Decolourization of Textile Dyes and Effluents", J. Appl. Biotechnol. Bioeng.  3, 430–435, 2017.
82.  M.A. hmad, M. Yousaf, A. Nasir, I.A. Bhatti, A. Mahmood, X. Fang, X. Jian, K. Kalantar-Zadeh, N. Mahmood, "Porous Eleocharis@MnPE Layered Hybrid for Synergistic Adsorption and Catalytic Biodegradation of Toxic Azo Dyes from Industrial Wastewater", Environ. Sci. Technol. 53, 2161–2170, 2019.
83.  M.Z. Hossen, M.E. Hussain, A. Hakim, K. Islam, M.N. Uddin, A.K. Azad, "Biodegradation of Reactive Textile Dye Novacron Super Black G by Free Cells of Newly Isolated Alcaligenes Faecalis AZ26 and Bacillus Spp Obtained from Textile Effluents", Heliyon. 5, 02068, 2019.
84.  R. Al-Tohamy, J. Sun, M.F. Fareed, E.R. Kenawy, S.S. Ali, "Ecofriendly Biodegradation of Reactive Black 5 by Newly Isolated Sterigmatomyces Halophilus SSA1575, Valued for Textile Azo Dye Wastewater Processing and Detoxification", Sci. Rep. 10, 12370, 2020.
85.  Q. Dai, S.Zhang, H. Liu, J. Huang, L. Li, "Sulfide-Mediated Azo Dye Degradation and Microbial Community Analysis in a Single-Chamber Air Cathode Microbial Fuel Cell", Bioelectrochemistry. 131, 107349, 2020. 
86.  R. V. Kandisa, S. K.V. Narayana, K. B. Shaik , R. Gopinath, "Dye Removal by Adsorption: A Review", J. bioremediat. Biodegrade. 7, 6, 2016.
87.  Y.Köseoğlu, M. Bay, M. Tan, A. Baykal, H. Sözeri, R. Topkaya, N. Akdoğan, "Magnetic and dielectric properties of Mn0. 2Ni0. 8Fe2O4 nanoparticles synthesized by PEG-assisted hydrothermal method", J. Nanopart .Res. 13, 2235-44, 2011.
88.  P.S .Kumar, G.J. Joshiba, C.C. Femina, P. Varshini, S. Priyadharshinia,M.S. Arun Karthicka , R. Jothirani , "A critical review on recent developments in the low-cost adsorption of dyes from wastewater ",  Desalination. Water. Treat. 172, 395-416, 2019. 
88.
89.  S.R. Mousavi, M. Asghari, N.M. Mahmoodi, "Chitosan-wrapped multiwalled carbon nanotube as filler within PEBA thin film nanocomposite (TFN) membrane to improve dye removal", Carbohydr. Polym. 237 , 116128,2020.
90.  Y. Wang, G. Xu, Z .Ren, X. Wei, W.Weng, P. Du, G.Shen, G. Han , "Mineralizer‐Assisted Hydrothermal Synthesis and Characterization of BiFeO3 Nanoparticles", J. Am. Ceram. Soc. 2007;90(8):2615-7. 
91.  M.M. Nejadian, N.M. Mahmoodi, C. Ghotbi, F. Khorasheh, "Novel heterojunction magnetic composite MIL-53 (Fe)/ZnFe2O4: Synthesis and photocatalytic pollutant degradation", Korean .J. Chem. Eng.  39 , 2713-2724, 2022.
92.    S. Verma, P. Joy, Y.Khollam, H. Potdar, S. Deshpande, "Synthesis of nanosized MgFe2O4 powders by microwave hydrothermal method", Mater. Lett. 58, 1092-5, 2004.
93.  Z. Li, B. Hou, Y. Xu, D. Wu, Y. Sun, Hu .W, Deng. F,"Comparative study of sol–gel-hydrothermal and sol–gel synthesis of titania–silica composite nanoparticles", J. Solid State .Chem. 178, 1395-405, 2005.
94.  H. Wang, Y. Ma, G. Yi, D. Chen, "Synthesis of Mn-doped Zn 2 SiO 4 rodlike nanoparticles through hydrothermal method", Mater. Chem. Phys.  82,414-8,2003. 
95.  R.S. Sabry, Y.K. Al-Haidarie, M.A. Kudhier, "Synthesis and photocatalytic activity of TiO2 nanoparticles prepared by sol–gel method", J. Solgel .Sci .Technol . 78, 299–306, 2016.
96.  M.T. Yagub, T.K. Sen, S. Afroze, H.M. Ang, "Dye and its Removal from aqueous solution by Adsorption: A review", Adv. Colloid .Interface .Sci. 209,172–84,2014.
97.  K. Hunger, "Industrial dyes: Chemistry, Properties, Applications", Germany. Wiley-VCH. 648,2007. 
98.  N.M. Mahmoodi, M.H. Saffar-Dastgerdi, "Clean Laccase immobilized nanobiocatalysts (graphene oxide - zeolite nanocomposites): From production to detailed biocatalytic degradation of organic pollutant", Appl. Catal. B: Environ. 268,118443,2020.
99.  B. Enayatpour, M .Rajabi, M. Yari, M.R, Mirkhan, F.Najafi, O.Moradi, A.K. Bharti, S. Agarwal, V.K. Gupta , "Adsorption/desorption study of proteins onto multi-walled carbon nanotubes and amino multi-walled carbon nanotubes surfaces as adsorbents", J .Mol .Liq. 231,566–71,2017.
100. A.T. Mansour, A. E. Alprol  , K. M. Abualnaja  , H.S. El-Beltagi, K.M. A. Ramadan  ,M.Ashour, "Dried Brown Seaweed’s Phytoremediation Potential for Methylene Blue Dye Removal from Aquatic Environments", Polymers. 14, 1375, 2022.
101. Z. karimi, A.Allahverdi, F. Oshani, "Investigation on the Removal of Dyes from Wastewater Using Alumina Composite Nano Adsorbent", J. Stud.color world, 10, 41-59, 2020 (In Persian). 
102.   B Kayranli , "Adsorption of textile dyes onto iron based waterworks sludge from aqueous solution; isotherm, kinetic and thermodynamic study", J. Chem. Eng, 173, 782-791, 2011.
103. M. Ghaedi, A. Ansari, M.H. Habibi, A.R. Asghari, "Removal of malachite green from aqueous solution by zinc oxide nanoparticle loaded on activated carbon: kinetics and isotherm study", J. Ind. Eng. Chem. 20,17–28, 2014.
104. M. Ghasemi, S. Mashhadi, M. Asif, I. Tyagi, S. Agarwal, V.K. Gupta, "Microwave-assisted synthesis of tetraethylenepentamine functionalized activated carbon with high adsorption capacity for Malachite green dye", J. Mol .Liq . 213,317–25,2016.
105. S.C.R. Santos, V.J.P. Vilar, R.A.R , Boaventura , "Waste metal hydroxide sludge as adsorbent for a reactive dye", J .Hazard. Mater. 153, 999-1008, 2008.
106. H. Wang, X. Yuan, G. Zeng, L. Leng, X. Peng, K. Liao, L. Peng , Z. Xiao, "Removal of malachite green dye from wastewater by different organic acid-modified natural adsorbent: kinetics, equilibriums, mechanisms, practical application, and disposal of dye-loaded adsorbent", Environ. Sci. Pollut. Res. 21, 11552–11564 ,2014.
107.   J. Castañeda-Díaz, T. Pavón-Silva, E. Gutiérrez-Segura, A. Colín-Cruz, "Electrocoagulation-Adsorption to Remove Anionic and Cationic Dyes from Aqueous Solution by PV-Energy", J. Chem . 2017, 14, 2017. 
108. B. Uçar, A. Güvenç, Ü. Mehmetoglu, "Use of Aluminium Hydroxide Sludge as Adsorbents for the Removal of Reactive Dyes: Equilibrium, Thermodynamic, and Kinetic Studies", Hydrol .Current .Res. 2 ,112, 2011.
109. P. Shraddha, M. Srinivas Kini , R. Selvaraj, "A review on adsorptive removal of dyes from wastewater by hydroxyapatite  nanocomposites", Environ. Sci. Pollut. Res. 28, 11835–11849 , 2021. 
110. P.P. Selvam, S. Preethi, P. Basakaralingam, N. Thinakaran, A. Sivasamy, S. Sivanesana,  "Removal of rhodamine B from aqueous solution by adsorption onto sodium montmorillonite", J. Hazard. Mater. 155,  39-44, 2008.  
111. S.C. Santos, R.A. Boaventura, "Treatment of a simulated textile wastewater in a sequencing batch reactor (SBR) with addition of a low-cost adsorbent", J. Hazard. Mater . 291, 74-82, 2015.
112. M. Shirmardi, A. H. Mahvi, B. Hashemzadeh, A. Naeimabadi, G. Hassani and M. Vosoughi Niri, "The adsorption of malachite green (MG) as a cationic dye onto functionalized multi walled carbon nanotubes", Korean. J. Chem. Eng . 30, 1603,2013.
113. Y. Yao, F. Xu, M. Chen, Z. Xu and Z. Zhu , "Adsorption behavior of methylene blue on carbon nanotubes" , Bioresour. Technol . 101, 3040,2010.
114. K. M. Abualnaja , A. E. Alprol, M. Ashour , A. T. Mansour, "Influencing Multi-Walled Carbon Nanotubes for the Removal of Ismate Violet 2R Dye from Wastewater: Isotherm, Kinetics, and Thermodynamic Studies ",Appl. Sci. 11, 4786, 2021. 
115. J. Ma, F. Yu, L. Zhou, L. Jin, M. Yang, J. Luan, Y. Tang, H. Fan, Z. Yuan and J. Chen, "Enhanced adsorptive removal of methyl orange and methylene blue from aqueous solution by alkali-activated multiwalled carbon nanotubes", ACS .Appl. Mater. Interfaces. 4, 5749,2012.
116. S. Yang, L. Wang, X. Zhang, W. Yang and G. Song, "Enhanced adsorption of Congo red dye by functionalized carbon nanotube/mixed metal oxides nanocomposites derived from layered double hydroxide precursor", Chem. Eng. J. 275, 315,2015.
117. W. Konicki, I. Pełech, E. Mijowska and I. Jasinska, "Adsorption of anionic dye Direct Red 23 onto magnetic multi-walled carbon nanotubes-Fe3C nanocomposite: Kinetics, equilibrium and thermodynamics",Chem. Eng. J . 210, 87, 2012.
118. S. M. R. Goddeti, M. Bhaumik, A. Maity , S. S. Ray, "Removal of Congo red from aqueous solution by adsorption using gum ghatti and acrylamide graft copolymer coated with zero valent iron", Int. J. Biol. Macromol.149, 21−30, 2020.
119. B. Nandi, A. Goswami, M. Purkait, "Removal of cationic dyes from aqueous solutions by kaolin: kinetic and equilibrium studies", Appl. Clay. Sci. 42,583–90,2009.
120. N.M. Mahmoodi, "Nickel ferrite nanoparticle: Synthesis,modification by surfactant and dye removal ability", Water. Air .Soil .Pollut. 224, 1419,2013.
121.   S. Dawood, and T.K. Sen, "Removal of anionic dye Congo red from aqueous solution by raw pine and acid-treated pine cone powder as adsorbent: equilibrium, thermodynamic, kinetics, mechanism and process design", Water. Res . 46,1933–46, 2012.
122. W.  Zhang, H. Li, X. Kan, Lei.Dong, H.Yan, Z. Jiang, H. Yang, A. Li, R. Cheng, "Adsorption of anionic dyes from aqueous solutions using chemically modified straw", Bioresour. Technol. 117, 40-47, 2013.
123. M.T. Yagub, T.K. Sen, H. Ang,  "Equilibrium, kinetics, and thermodynamics of methylene blue adsorption by pine tree leaves", Water .Air. Soil. Pollut. 223,5267–82, 2012.
124. W. Liu, C. Yao , M. Wang, J. Ji, L. Ying , C. Fu , " Kinetics and thermodynamics characteristics of cationic yellow X‐GL adsorption on attapulgite/rice hull‐based activated carbon nanocomposites " , Environ. Prog .Sust .Energ. 32,655–622012, 2013. 
125. N.B. Singh, K. Rachna, A. Agrawal , "Methylene blue dye removal from water by nickel ferrite polyaniline nanocomposite", J .Sci. Ind. Res. 78,118–121,2019. 
126. A. Gouthaman, J . Auslin Asir, A . Gnanaprakasam, V.M. Sivakumar, M. Thirumarimurugan, A . Mohamed , A. Riswan, R .S. Azarudeen , "Enhanced dye removal using polymeric nanocomposite through incorporation of Ag doped ZnO nanoparticles: Synthesis and characterization", J .Hazard .Mater. 373,493-503, 2019. 
127. N.M. Mahmoodi , "Synthesis of amine-functionalized magnetic ferrite nanoparticle and its dye removal ability", J . Environ .Eng . 139, 1382–1390, 2013.
128. N.M. Mahmoodi, "Synthesis of core–shell magnetic adsorbent nanoparticle and selectivity analysis for binary system dye removal", J. Ind .Eng. Chem. 20, 2050–2058, 2014.
129. D. de . Oliveira Lopes, L. Oliveira Santos, E.D. Nascimento, A.D. Vieira de Souza, F.A.de. Oliveira Carvalho, "Adsorption of acid yellow dye 17 on activated carbon prepared from Euterpe oleracea: kinetic and thermodynamic studies", Research. Society and Development. 11, 2022. 
130. F. Largo, R. Haounati, S.Akhouairi, H.Ouachtak, R.El Haouti, A. El , Guerdaoui, N. Hafid, D. M.F.Santos, F. Akbal, A. Kuleyin, A. Jada, A. AitAdd , "Adsorptive removal of both cationic and anionic dyes by using sepiolite clay mineral as adsorbent: Experimental and molecular dynamic simulation studies", J. Mol. Liq. 318, 114247,2020. 
131. Z. Hussain, N. Chang, J.q. Sun, S. Xiang, T.Ayaz , H.Zhang, H.Wang, "Modification of coal fly ash and its use as low-cost adsorbent for the removal of directive, acid and reactive dyes" , J. Hazard. Mater. 422, 126778, 2022. 
132.   M. Sarker, S. Shin, J.H. Jeong, S.H. Jhung , "Mesoporous metal-organic framework PCN-222(Fe): promising adsorbent for removal of big anionic and cationic dyes from water", Chem .Eng. J. 371,252– 259, 2019. 
133. B. Tanhaei, A. Ayati, M. Sillanpää , "Magnetic xanthate modified chitosan as an emerging adsorbent for cationic azo dyes removal: kinetic, thermodynamic and isothermal studies", Int. J .Biol. Macromo. 121,1126–1134, 2019. 
134. A. Abd-Elhamid, Elbadawy A. Kamoun, A. El-Shanshory, H. Soliman, H. Aly, "Evaluation of graphene oxide-activated carbon as effective composite adsorbent toward the removal of cationic dyes: composite preparation, characterization and adsorption parameters", J. Mol. Liq. 279,530–539, 2019. 
135. N. M. Mahmoodi , Z. Mokhtari-Shourijeh, and J. Abdi, "Preparation of Mesoporous Polyvinyl Alcohol/Chitosan/Silica Composite Nanofiber and Dye Removal from Wastewater", Environ. Prog. Sustain. 38, S100-S109, 2019.
136. O. Moradi, S. Maraghe, S. Arab-Salmanabadi, "Removal of safranin dye using graphene oxide, activated carbon nanocomposites, aluminum hydroxide and oxide graphene nanoparticles, activated carbon and cerium oxide nanoparticles", J. Color.Sci. Tech. 2012-1123, 2021.
137. X. Inthapanya, S. Wu, Z. Han, G. Zeng, M. Wu, C. Yang , "Adsorptive removal of anionic dye using calcined oyster shells: isotherms, kinetics, and thermodynamics", Environ .Sci .Pollut. Res. 26,5944– 5954,2019.
138. Z. Harrache, M. Abbas, T. Aksil, M. Trari, "Thermodynamic and kinetics studies on adsorption of indigo carmine from aqueous solution by activated carbon", Microchem .J . 144,180–189, 2019.
139. G. Janet Joshiba, P. Senthil Kumar, Gayathri Rangasamy, P. Tsopbou Ngueagni, G. Pooja, G. Bharat Balji, Krishnapandi Alagumalai, Hamed A. El-Serehy, "Iron doped activated carbon for effective removal of tartrazine and methylene blue dye from the aquatic systems: Kinetics, isotherms, thermodynamics and desorption studies", Environ. Res. 215, 114317, 2022. 
140. K. Jedynak, D. Wideł, N. Rędzia, "Removal of rhodamine B (a basic dye) and acid yellow 17 (an acidic dye) from aqueous solutions by ordered mesoporous carbon and commercial activated carbon", J. Colloid. Interface. Sci.3, 30, 2019.
141. Aliakbar Dehno Khalaji , "of CuO/Cu2O nanocomposite to removal of methyl orange dye from aqueous solution ", J. Color. Sci. Tech. 2101-1127, 2021.
142. M. Heydari, M. Gharagozlou , M. Ghahari, "Synthesis and Application of Nanocomposite Containing Metal-Organic Framework and Magnetic Nanoparticles in Silica Matrix for Decolorization of Methylene Blue", J. Color. Sci. Tech. 15, 103-115, 2021.
143. Sh. Shariati , M. Bostani1 , F. Shariati, S. Rahnama, "Application of Magnetite Nanoparticle Modified Azolla as an Adsorbent for Removal of Brilliant Blue Dye", J. Color .Sci. Tech. 15, 131-141, 2021.
144. H. Ghasemzadeh Mohammadi ,A. Keshtkar Vanashi ,M. Taghipour Ziaratgah ,M. Pirgholi, "Nanocomposite Hydrogels Based on Gelatin and Nickel Oxide Nanoparticles for Adsorption of Cationic Pollutants", J. Color .Sci. Tech. 14, 295-310, 2021