مروری بر مشخصه‌های پوشش‌های الماس مصنوعی تهیه شده به روش ‌رسوب‌دهی شیمیایی از فاز بخار (CVD)

نوع مقاله : مقاله مروری

نویسندگان

1 دانشیار، گروه پژوهشی نانو فناوری رنگ، پژوهشکده پوشش های سطح و فناوری های نوین، پژوهشگاه رنگ

2 دانشجوی دکترا، دانشکده مهندسی انرژی، دانشگاه شهید بهشتی

3 استادیار، گروه پژوهشی علوم و فناوری چاپ، پژوهشکده فیزیک رنگ

چکیده

الماس در مقایسه با سایر مواد، دارای خواص فیزیکی بسیار ‌ویژه‌ای ‌می‌باشد. علیرغم این ویژگی‌ها، کاربردهای عملی آن در صنعت، به علت کمیابی و قیمت بالا، بسیار محدود است. با توجه به پیشرفت‌های اخیر فناوری، تهیه پوشش‌های نازک الماس مصنوعی بر سطح بسترهای مختلف امکان‌پذیر گشته است. به عنوان مثال، اعمال یک لایه الماس مصنوعی به روش ‌رسوب‌دهی شیمیایی از فاز بخار (CVD) بر سطح ابزارهای مورد استفاده در صنعت ماشین‌کاری، منجر به بهبود کارایی این ابزارها خواهد شد. در حال حاضر تقاضای استفاده صنعتی از پوشش‌های الماس مصنوعی، به دلیل خواصی چون مقاومت سایشی بالا، سختی فوق العاده و ضریب اصطکاک کم، به شدت افزایش یافته است و تحقیقات وسیعی جهت رفع عیوب، بهبود خواص و گسترش این دسته از پوشش‌ها در جریان ‌می‌باشد. با این حال، یکی از مشکلات عمده پوشش‌های الماس مصنوعی این است که این پوشش‌ها تحت بارگذاری بالا از سطح قطعه جدا ‌می‌شوند; به همین جهت تلاش محققان، بر افزایش چسبندگی این پوشش‌ها تمرکز یافته است. لازم به ذکر است که به منظور دستیابی به چسبندگی مناسب در این پوشش‌ها، می‌بایست بسیاری از خصوصیات ‌سامانه پوشش- بستر، از قبیل ضخامت بهینه پوشش و به حداقل رساندن تنش حرارتی پسماند، در نظر گرفته شود. بنابراین، به منظور دستیابی به پوشش‌های الماس مصنوعی با خواص منحصر بفرد، لازم است که ریزساختار و معماری پوشش‌ها به دقت طراحی گردد. هدف از مقاله حاضر، بررسی تحقیقات صورت گرفته در زمینه مشخصه‌ها و بهبود عملکرد این خانواده مهم از پوشش‌های محافظ، ‌می‌باشد.

کلیدواژه‌ها

موضوعات


عنوان مقاله [English]

A Review of the Characteristics of Synthetic Diamond Coatings Prepared by Chemical Vapor Deposition (CVD) Technique

نویسندگان [English]

  • Sara Khamseh 1
  • elahe sharifi 2
  • Mohsen Mohammad Raei Nayini 3
1 Department of Nanomaterials and Nanocoatings, Institute for Colour Science and Technology
2 Faculty of Energy Engineering, Shahid Beheshti University
3 Department of Printing Science and Technology, Institute for Color Science and Technology
چکیده [English]

Diamond has unique properties compared to other materials. Despite these features, its application in the industry is minimal due to its scarcity and high price. Due to recent technological advances, it has become possible to deposit thin synthetic diamond coatings on the surface of various substrates such as metal and ceramics. For example, tungsten carbide–cobalt composites (WC-Co) are common materials in tribological applications and cutting tools that synthetic diamond coatings can be deposited on them. Reports in this field show that the deposition of synthetic diamond coatings by chemical vapor deposition (CVD) on the surface of carbide tools significantly improves their mechanical and tribological properties and leads to improved performance. The industrial use of synthetic diamond coatings has increased due to high wear resistance, excellent hardness, and low friction coefficient. For this reason, extensive research has been done to eliminate defects, improve the properties, and expand this category of coatings. However, one of the significant problems of synthetic diamond coatings is their low adhesion strength on the tool surfaces; Therefore, many researchers have focused on increasing the adhesion of these coatings. To achieve proper adhesion in these coatings, many characteristics of the coating-substrate system, such as the optimal thickness of the coating and minimizing the residual thermal stress, must be considered. Therefore, to attain synthetic diamond coatings with unique properties, it is necessary to design the microstructure and architecture of the coatings carefully. This article aims to review the researches conducted to improve the performance of diamond protective coatings.
 

کلیدواژه‌ها [English]

  • Synthetic diamond coatings
  • Chemical vapor deposition (CVD)
  • Tribological performance
  • Adhesion
  • Surface modification
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